We show that the intersection of three subgroups in a free group is related to the computation of the third homotopy group π3. This generalizes a result of Gutierrez–Ratcliffe who relate the intersection of two subgroups with the computation of π2. Let K be a two-dimensional CW-complex with subcomplexes K1, K2, K3 such that K = K1 ∪ K2 ∪ K3 and K1 ∩ K2 ∩ K3 is the 1-skeleton K1 of K. We construct a natural homomorphism of π1(K)-modules [Formula: see text] where Ri = ker {π1(K1) → π1(Ki)}, i = 1,2,3 and the action of π1(K) = F/R1R2R3 on the right-hand abelian group is defined via conjugation in F. In certain cases, the defined map is an isomorphism. Finally, we discuss certain applications of the above map to group homology.