Synthesis, crystal structure, spectral, dielectric characteristics and conduction mechanism of two novel carboxylates of 1-benzhydrylpiperazine

2015 ◽  
Vol 146 (12) ◽  
pp. 2007-2020 ◽  
Author(s):  
Intissar Wacharine ◽  
Arto Valkonen ◽  
Mohamed Rzaigui ◽  
Wajda Smirani
2017 ◽  
Vol 28 (6) ◽  
pp. 3159-3174 ◽  
Author(s):  
Maha Mathlouthi ◽  
Abdelhamid Chiheb Dhieb ◽  
Arto Valkonen ◽  
Mohamed Rzaigui ◽  
Wajda Smirani

Crystals ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 399
Author(s):  
Djoko Triyono ◽  
Ismi Purnamasari ◽  
Rifqi Almusawi Rafsanjani

The LaFe1−xZrxO3 (x = 0.01, 0.05) ceramics were prepared by sol-gel and annealing method and studied by XRD, Raman scattering analysis, SEM, and impedance spectroscopy method. The crystal structure and phonon characteristics analysis revealed that the crystal structure tends to preserve its ideal orthorhombic structure, following the increase in driving force of the Fe/ZrO6 octahedral tilting. The frequency-dependent dielectric parameters at each temperature decreased with increasing Zr content. The temperature dependence dielectric relaxation and dc conduction mechanism satisfied the Arrhenius law and increased with increasing Zr content. The activation energy ranged from 0.30 to 0.50 eV and was similar in the relaxation and conduction mechanisms, indicating that both transport mechanisms were based on a similar mechanism.


2016 ◽  
Vol 42 (12) ◽  
pp. 13395-13403 ◽  
Author(s):  
Jie Wei ◽  
Yang Liu ◽  
Xiaofei Bai ◽  
Chen Li ◽  
Yalong Liu ◽  
...  

2019 ◽  
Vol 45 (8) ◽  
pp. 10170-10175 ◽  
Author(s):  
Gang Wang ◽  
Dainan Zhang ◽  
Fang Xu ◽  
Xin Huang ◽  
Yan Yang ◽  
...  

1997 ◽  
Vol 12 (6) ◽  
pp. 1437-1440 ◽  
Author(s):  
Hyo-Jong Lee ◽  
Kug-Sun Hong ◽  
In-Tae Kim

The microwave dielectric characteristics and crystal structure of the Zn(NbxTa1−x)2O6 and Mg(NbxTa1−x)2O6 systems have been investigated. It was found that both systems exhibited a morphotropic phase transition. Based on the results it was suggested that permittivity and temperature coefficient of resonant frequency depend more on crystal structure rather than on chemical composition. It was also suggested that a two-phase mixture is better than a solid solution for achieving both high quality factor and good temperature stability.


2006 ◽  
Vol 514-516 ◽  
pp. 250-254 ◽  
Author(s):  
Andrei N. Salak ◽  
Nikolai P. Vyshatko ◽  
Andréi L. Kholkin ◽  
Victor M. Ferreira ◽  
Nikolay M. Olekhnovich ◽  
...  

Lead-free relaxor ceramics based on sodium-bismuth titanate, (1-x)(Na1/2Bi1/2)TiO3 - xLa(Mg1/2Ti1/2)O3 [(1-x)NBT-xLMT] (0≤x≤0.25), were prepared by both the conventional mixed oxide method and by the Pechini route, and their crystal structure and dielectric properties were investigated. All the compositions studied were found to possess a rhombohedrally distorted crystal lattice at room temperature. A distortion degree of the unit cell decreases and its volume increases with LMT content. The temperature of the dielectric permittivity maximum does not change with increasing substitution rate. As x is increased, the frequency-dependent dielectric peaks are flattened. The compositional evolution of structure and dielectric characteristics of the ceramics obtained are analysed and discussed in respect to size, charge and polarizability of the cations involved.


2000 ◽  
Vol 35 (1) ◽  
pp. 15-24 ◽  
Author(s):  
C.O Paiva-Santos ◽  
C.F Oliveira ◽  
W.C Las ◽  
M.A Zaghete ◽  
J.A Varela ◽  
...  

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