impedance spectroscopy
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2022 ◽  
Vol 12 (2) ◽  
pp. 885
Author(s):  
Ahmed Yahia Kallel ◽  
Viktor Petrychenko ◽  
Olfa Kanoun

Several studies show that impedance spectroscopy is a suitable method for online battery diagnosis and State-of-Health (SoH) estimation. However, the most common method is to model the acquired impedance spectrum with equivalent circuits and focus on the most sensitive parameters, namely the charge-transfer resistance. This paper introduces first a detailed model of a battery cell, which is then simplified and adapted to the observable spectrum behavior. Based on the physical meaning of the model parameters, we propose a novel approach for SoH assessment combining parameters of the impedance spectrum by building the ratio of the solid electrolyte interphase (SEI) resistance to the total resistance of SEI and the charge transfer. This ratio characterizes the charge-transfer efficiency at the electrodes’ surfaces and should decrease systematically with SoH. Four different cells of the same type were cycled 400 times for the method validation, and impedance spectroscopy was performed at every 50th cycle. The results show a systematic correlation between the proposed ratio and the number of cycles on individual cell parameters, which build the basis of a novel online method of SoH assessment.


2022 ◽  
Vol 12 (1) ◽  
Author(s):  
Jiajun Li ◽  
Xiaoxue Jiang ◽  
Faheem Khan ◽  
Xuanjie Ye ◽  
Shuren Wang ◽  
...  

AbstractElectrochemical impedance spectroscopy (EIS) has been used in various applications, such as metal corrosion monitoring. However, many conventional corrosion monitoring setups are bulky and inconvenient for in-situ testing. The purpose of this work is to reduce the size of the whole corrosion monitoring system. We utilized EIS to design a field deployable impedance-based corrosion sensor (FDICS), capable of performing in-situ EIS analysis. Experiments verified the sensor’s accuracy, and the results showed that the sensor performed similarly to a bench-top EIS machine when we tested on circuit models. Furthermore, we used the proposed FDICS to monitor a metal corrosion experiment and performed EIS. The result showed that the proposed FDICS is able to obtain the sample’s impedance spectroscopy, which could help researchers test its corrosion severity on a metallic sample in-situ. Compared to other bulky conventional setups, our device eliminates the design complexity while still showing insights into the corrosion reaction.


2022 ◽  
Vol 12 (2) ◽  
pp. 591
Author(s):  
Ahmed Yahia Kallel ◽  
Zheng Hu ◽  
Olfa Kanoun

For embedded impedance spectroscopy, a suitable method for analyzing AC signals needs to be carefully chosen to overcome limited processing capability and memory availability. This paper compares various methods, including the fast Fourier transform (FFT), the FFT with barycenter correction, the FFT with windowing, the Goertzel filter, the discrete-time Fourier transform (DTFT), and sine fitting using linear or nonlinear least squares, and cross-correlation, for analyzing AC signals in terms of speed, memory requirements, amplitude measurement accuracy, and phase measurement accuracy. These methods are implemented in reference systems with and without hardware acceleration for validation. The investigation results show that the Goertzel algorithm has the best overall performance when hardware acceleration is excluded or in the case of memory constraints. In implementations with hardware acceleration, the FFT with barycentre correction stands out. The linear sine fitting method provides the most accurate amplitude and phase determinations at the expense of speed and memory requirements.


Materials ◽  
2022 ◽  
Vol 15 (2) ◽  
pp. 413
Author(s):  
Małgorzata Adamczyk-Habrajska ◽  
Beata Wodecka-Duś ◽  
Tomasz Goryczka ◽  
Diana Szalbot ◽  
Mateusz Bara ◽  
...  

Lanthanum-modified BaTiO3 electroceramic materials have superior dielectric and piezoelectric properties. Ba0.996La0.004Ti0.999O3 (BLT4) seems to be a serious candidate for ultracondensator applications. This manuscript describes the results of hafnium and europium modification of BLT 4 ceramics. The pure and doped ceramic materials were synthesized by the conventional mixed oxide method. The microstructure of obtained samples was examined by scanning electron microscope. The investigations reveal strong correlations between the presence of admixture and the grain size, which was especially visible in the case of the hafnium dopant. The frequency and temperature dielectric characteristics measurements revealed a decrease in electric permittivity. Moreover, the impedance spectroscopy investigations showed severe changes in grains and grain-boundary resistivity, which was connected with changes in electric conductivity.


Energies ◽  
2022 ◽  
Vol 15 (1) ◽  
pp. 386
Author(s):  
Lei Zhao ◽  
Haifeng Dai ◽  
Fenglai Pei ◽  
Pingwen Ming ◽  
Xuezhe Wei ◽  
...  

Electrochemical impedance spectroscopy is one of the important tools for the performance analysis and diagnosis of proton exchange membrane fuel cells. The equivalent circuit model is an effective method for electrochemical impedance spectroscopy resolution. In this paper, four typical equivalent circuit models are selected to comprehensively compare and analyze the difference in the fitting results of the models for the electrochemical impedance spectroscopy under different working conditions (inlet pressure, stoichiometry, and humidity) from the perspective of the fitting accuracy, change trend of the model parameters, and the goodness of fit. The results show that the fitting accuracy of the model with the Warburg element is the best for all under each working condition. When considering the goodness of fit, the model with constant phase components is the best choice for fitting electrochemical impedance spectroscopy under different inlet pressure and air stoichiometry. However, under different air humidity, the model with the Warburg element is best. This work can help to promote the development of internal state analysis, estimation, and diagnosis of the fuel cell based on the equivalent circuit modeling of electrochemical impedance spectroscopy.


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