Theoretical Aspects of Dynamic Nuclear Polarization in the Solid State: The Influence of High Radical Concentrations on the Solid Effect and Cross Effect Mechanisms

2012 ◽  
Vol 43 (1-2) ◽  
pp. 21-41 ◽  
Author(s):  
Y. Hovav ◽  
O. Levinkron ◽  
A. Feintuch ◽  
S. Vega
Keyword(s):  
Solid State ◽  
Dynamic Nuclear Polarization ◽  
Nuclear Polarization ◽  
Cross Effect ◽  
Solid Effect

Dynamic nuclear polarization in the solid state: a transition between the cross effect and the solid effect

2012 ◽  
Vol 14 (16) ◽  
pp. 5729 ◽  
Author(s):  
Daphna Shimon ◽  
Yonatan Hovav ◽  
Akiva Feintuch ◽  
Daniella Goldfarb ◽  
Shimon Vega
Keyword(s):  
Solid State ◽  
Dynamic Nuclear Polarization ◽  
Nuclear Polarization ◽  
Cross Effect ◽  
Solid Effect ◽  
The Cross

Static 1H dynamic nuclear polarization with the biradical TOTAPOL: a transition between the solid effect and the cross effect

2014 ◽  
Vol 16 (14) ◽  
pp. 6687-6699 ◽  
Author(s):  
Daphna Shimon ◽  
Akiva Feintuch ◽  
Daniella Goldfarb ◽  
Shimon Vega
Keyword(s):  
High Temperatures ◽  
Dynamic Nuclear Polarization ◽  
Low Temperatures ◽  
Nuclear Polarization ◽  
Cross Effect ◽  
Solid Effect ◽  
The Cross

Static 1H-DNP with TOTAPOL: the solid effect (SE) dominant at low temperatures; the cross effect (CE) dominant at high temperatures; and DNP-buildup: Tbu(SE) < Tbu(CE).

Bis-Gadolinium Complexes for Solid Effect and Cross Effect Dynamic Nuclear Polarization

2017 ◽  
Vol 129 (15) ◽  
pp. 4359-4363
Author(s):  
Monu Kaushik ◽  
Mian Qi ◽  
Adelheid Godt ◽  
Björn Corzilius
Keyword(s):  
Dynamic Nuclear Polarization ◽  
Nuclear Polarization ◽  
Cross Effect ◽  
Gadolinium Complexes ◽  
Solid Effect

scholarly journals Optimizing nitroxide biradicals for cross-effect MAS-DNP: the role of g-tensors’ distance

2020 ◽  
Vol 22 (6) ◽  
pp. 3643-3652 ◽  
Author(s):  
Frédéric Mentink-Vigier
Keyword(s):  
Solid State ◽  
Dynamic Nuclear Polarization ◽  
Solid State Nmr ◽  
Nuclear Polarization ◽  
Magic Angle Spinning ◽  
Magic Angle ◽  
Cross Effect ◽  
Angle Spinning

Nitroxide biradicals are common polarizing agents used to enhance the sensitivity of solid-state NMR experiments via Magic Angle Spinning Dynamic Nuclear Polarization (MAS-DNP).

scholarly journals Correction: Theory of solid effect and cross effect dynamic nuclear polarization with half-integer high-spin metal polarizing agents in rotating solids

2016 ◽  
Vol 18 (42) ◽  
pp. 29643-29643 ◽  
Author(s):  
Björn Corzilius
Keyword(s):  
High Spin ◽  
Dynamic Nuclear Polarization ◽  
Nuclear Polarization ◽  
Chem Phys ◽  
Cross Effect ◽  
Half Integer ◽  
Solid Effect ◽  
Phys Chem Chem Phys

Correction for ‘Theory of solid effect and cross effect dynamic nuclear polarization with half-integer high-spin metal polarizing agents in rotating solids’ by Björn Corzilius et al., Phys. Chem. Chem. Phys., 2016, DOI: 10.1039/c6cp04621e.

scholarly journals Theory of solid effect and cross effect dynamic nuclear polarization with half-integer high-spin metal polarizing agents in rotating solids

2016 ◽  
Vol 18 (39) ◽  
pp. 27190-27204 ◽  
Author(s):  
Björn Corzilius
Keyword(s):  
High Spin ◽  
Dynamic Nuclear Polarization ◽  
Nuclear Polarization ◽  
Theoretical Description ◽  
Cross Effect ◽  
Half Integer ◽  
Solid Effect ◽  
Spin Properties

Detailed theoretical description of high-spin properties of metal polarizing agents, especially Gd3+, for solid effect and cross effect DNP.

Bis-Gadolinium Complexes for Solid Effect and Cross Effect Dynamic Nuclear Polarization

2017 ◽  
Vol 56 (15) ◽  
pp. 4295-4299 ◽  
Author(s):  
Monu Kaushik ◽  
Mian Qi ◽  
Adelheid Godt ◽  
Björn Corzilius
Keyword(s):  
Dynamic Nuclear Polarization ◽  
Nuclear Polarization ◽  
Cross Effect ◽  
Gadolinium Complexes ◽  
Solid Effect
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