Behaviour and Quantification Studies of Terbacil and Lenacil in Environmental Samples Using Cyclic and Adsorptive Stripping Voltammetry at Hanging Mercury Drop Electrode

2006 ◽  
Vol 128 (1-3) ◽  
pp. 359-368 ◽  
Author(s):  
T. Thriveni ◽  
J. Rajesh Kumar ◽  
D. Sujatha ◽  
N. Y. Sreedhar
2016 ◽  
Vol 2016 ◽  
pp. 1-6 ◽  
Author(s):  
Dariusz Guziejewski ◽  
Agnieszka Nosal-Wiercińska ◽  
Sławomira Skrzypek ◽  
Witold Ciesielski ◽  
Sylwia Smarzewska

The aim of the research was the use of square wave adsorptive stripping voltammetry (SWAdSV) in conjunction with a hanging mercury drop electrode (HMDE) for the determination of nitrothal-isopropyl. It was found that optimal SW technique parameters were frequency, 200 Hz; amplitude, 50 mV; and step potential, 5 mV. Accumulation time and potential were studied to select the optimal conditions in adsorptive stripping voltammetry: 45 s at 0.0 V, respectively. The calibration curve (SWSV) was linear in the nitrothal-isopropyl concentration range from 2.0 × 10−7 to 2.0 × 10−6 mol L−1 with detection limit of 3.46 × 10−8 mol L−1. The repeatability of the method was determined at a nitrothal-isopropyl concentration level equal to 6.0 × 10−7 mol L−1 and expressed as RSD = 5.5% (n=6). The proposed method was successfully validated by studying the recovery of nitrothal-isopropyl in spiked environmental samples.


2001 ◽  
Vol 137 (3-4) ◽  
pp. 215-220 ◽  
Author(s):  
Mohamed S. Ibrahim ◽  
Mohamed S. El-Maazawi ◽  
Khaled M. Al-Magboul ◽  
Moustafa M. Kamal

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