scholarly journals First Electrochemical Method of Nitrothal-Isopropyl Determination in Water Samples

2016 ◽  
Vol 2016 ◽  
pp. 1-6 ◽  
Author(s):  
Dariusz Guziejewski ◽  
Agnieszka Nosal-Wiercińska ◽  
Sławomira Skrzypek ◽  
Witold Ciesielski ◽  
Sylwia Smarzewska
Keyword(s):  
Environmental Samples ◽  
Electrochemical Method ◽  
Concentration Level ◽  
Stripping Voltammetry ◽  
Adsorptive Stripping Voltammetry ◽  
Hanging Mercury Drop Electrode ◽  
Optimal Conditions ◽  
Step Potential ◽  
Accumulation Time

The aim of the research was the use of square wave adsorptive stripping voltammetry (SWAdSV) in conjunction with a hanging mercury drop electrode (HMDE) for the determination of nitrothal-isopropyl. It was found that optimal SW technique parameters were frequency, 200 Hz; amplitude, 50 mV; and step potential, 5 mV. Accumulation time and potential were studied to select the optimal conditions in adsorptive stripping voltammetry: 45 s at 0.0 V, respectively. The calibration curve (SWSV) was linear in the nitrothal-isopropyl concentration range from 2.0 × 10−7 to 2.0 × 10−6 mol L−1 with detection limit of 3.46 × 10−8 mol L−1. The repeatability of the method was determined at a nitrothal-isopropyl concentration level equal to 6.0 × 10−7 mol L−1 and expressed as RSD = 5.5% (n=6). The proposed method was successfully validated by studying the recovery of nitrothal-isopropyl in spiked environmental samples.

Determination of Amitraz Pesticide by Adsorptive Stripping Voltammetry on the Hanging Mercury Drop Electrode

2001 ◽  
Vol 137 (3-4) ◽  
pp. 215-220 ◽  
Author(s):  
Mohamed S. Ibrahim ◽  
Mohamed S. El-Maazawi ◽  
Khaled M. Al-Magboul ◽  
Moustafa M. Kamal
Keyword(s):  
Stripping Voltammetry ◽  
Adsorptive Stripping Voltammetry ◽  
Hanging Mercury Drop Electrode ◽  
Mercury Drop Electrode

scholarly journals The determination of titanium contained in Tytanit biostimulant employed to improve crops performance in natural environmental samples

2017 ◽  
Vol 71 (2) ◽  
pp. 115
Author(s):  
Joanna Wasąg ◽  
Malgorzata Grabarczyk
Keyword(s):  
Natural Water ◽  
Water Samples ◽  
Environmental Samples ◽  
Stripping Voltammetry ◽  
Environmental Water ◽  
Adsorptive Stripping Voltammetry ◽  
Environmental Water Samples ◽  
Chloranilic Acid ◽  
Titanium Complex

<p>The purpose of this work was to determinate the amount of titanium in different environmental water samples spiked with crop biostimulant Tytanit. The measurements were conducted using adsorptive stripping voltammetry (AdSV). The titanium complex with chloranilic acid was accumulated on mercury film silver based electrode (Hg(Ag)FE) at the potential -0.3 V. The analysis of natural water samples enriched with Tytanit, collected in the eastern part ofPolandconfirms that this procedure is fast and essential for the determination of titanium in environmental water samples.</p>

scholarly journals STUDI OPTIMASI PENENTUAN Cu(II) DENGAN MENGGUNAKAN KALKON SEBAGAI PENGOMPLEK SECARA VOLTAMMETRI STRIPPING ADSORPTIF (AdSV)

2015 ◽  
Vol 4 (2) ◽  
pp. 55
Author(s):  
Deswati ◽  
Hamzar Suyani ◽  
Bustanul Arifin ◽  
Imelda ◽  
Yunita Salamah
Keyword(s):  
Stripping Voltammetry ◽  
Adsorptive Stripping Voltammetry ◽  
Complexing Agent ◽  
Trace Concentration ◽  
Accumulation Time ◽  
Sample Concentration ◽  
Accumulation Potential ◽  
Ultra Trace ◽  
Determination Of Copper

 ABSTRACT The research about determination of Cu(II) by adsorptive stripping voltammetry (AdSV) was conducted. AdSV method was applied to the determination of copper in ultra trace concentration. The parameters of ligand, accumulation potential, accumulation time, pH and ligand concentration was studied. Calcon was found as complexing agent that give the highest peak current. The optimum condition are accumulation potential -0,7 V, accumulation time 60 s, pH 10, and calcon concentration 0.12 mM. The relative standar deviation (n=8) at 10 µg/L standard concentration were obtained 4,27 %. This method was applied to determination of Cu(II) in sample from Batang Air Dingin, Lubuk Minturun and Muara Padang. The sample concentration were 4,778 µg/L and 5,189 µg/L for Batang Air Dingin and Muara Padang, respectively. The recovery of this method was studied for sample from Muara Padang and 98,31 % was obtained. Key words :   Adsorptive, Stripping, Voltammetry, Calcon and Copper    

scholarly journals STUDI OPTIMASI KROMIUM (VI) DALAM AIR LAUT SECARA VOLTAMMETRI STRIPPING ADSORPTIF

2015 ◽  
Vol 3 (1) ◽  
pp. 22
Author(s):  
Deswati ◽  
Hamzar Suryani ◽  
Imelda ◽  
Yulia
Keyword(s):  
Electrolyte Concentration ◽  
Sea Water ◽  
Direct Determination ◽  
Stripping Voltammetry ◽  
Adsorptive Stripping Voltammetry ◽  
Optimum Conditions ◽  
Accumulation Time ◽  
Accumulation Potential ◽  
Relative Standard

 ABSTRACT Study of optimation chromium (VI) in sea water by adsorptive stripping voltammetry has been done. The aim of this method to get optimum conditions for determination of Cr(VI). Adsorptive stripping voltammetry (AdSV) has been used for the ultra trace determination of chromium using 2,2’- bipyridin as ligand. Parameters were done, like accumulation time, concentration of ligand, pH, accumulation potential, electrolyte concentration and catalyst concentration. In this case, the optimum conditions were reached in accumulation time 80 second, pH 5.0, concentration of 2,2’- bipyridin 10 μM, accumulation potential -0,6 Volt and electrolyte concentration (NH4Cl) 0,1 M. In the optimum conditions, a linear calibration graph was obtained with correlation coefficient of 0.9971, the relative standard deviation was 15.06 % for eight replicates (n = 8) measurements of 10 μg/L of Cr(VI). The detection limit method was 0.1692 μg/L. The method was applied to the direct determination of Cr(VI) in sea water around Muara Padang water. Concentration Cr(VI) in sample was equal to 0.9684 μg/L with recovery of 90.23 %. Keywords : optimation, chromium, adsorptive, stripping, voltammetry

Determination of methoprotryne and terbutryn by adsorptive stripping voltammetry on the hanging mercury drop electrode

The Analyst ◽  
1993 ◽  
Vol 118 (11) ◽  
pp. 1405-1410 ◽  
Author(s):  
María Pedrero ◽  
Victoria Calvo ◽  
F. Javier Manuel de Villena ◽  
Jose M. Pingarrón ◽  
Luis M. Polo
Keyword(s):  
Stripping Voltammetry ◽  
Adsorptive Stripping Voltammetry ◽  
Hanging Mercury Drop Electrode ◽  
Mercury Drop Electrode
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