Crystal structure, phonon characteristic, and intrinsic properties of Sm(Mg1/2Sn1/2)O3 double perovskite ceramic

2017 ◽  
Vol 28 (19) ◽  
pp. 14156-14162 ◽  
Author(s):  
Huiling Chen ◽  
Chao Xing ◽  
Jianzhu Li ◽  
Hengyang Qiao ◽  
Jun Yang ◽  
...  
2005 ◽  
Vol 631 (11) ◽  
pp. 2127-2130 ◽  
Author(s):  
L. Ortega-San Martín ◽  
J. P. Chapman ◽  
G. Cuello ◽  
J. González-Calbet ◽  
M. I. Arriortua ◽  
...  

Author(s):  
Gennady V. Bazuev ◽  
Alexander E. Teplykh ◽  
Alexander V. Korolev ◽  
Evgeny G. Gerasimov ◽  
Pavel B. Terentev

2014 ◽  
Vol 47 (4) ◽  
pp. 1395-1401 ◽  
Author(s):  
Carlos A. López ◽  
José C. Pedregosa ◽  
Diego G. Lamas ◽  
José A. Alonso

The crystal structure and ionic conductivity properties of a novel microcrystalline Sr11Mo4O23ceramic material are presented. This material has been prepared by thermal treatment up to 1473 K, in air, of previously decomposed citrate precursors. The complex crystal structure was refined from combined X-ray powder diffraction and neutron powder diffraction data. The formula of this phase can be rewritten as Sr1.75□0.25SrMoO5.75, highlighting the relationship with double perovskitesA2B′B′′O6. At room temperature, the crystal structure is tetragonal in space groupI41/a, witha= 11.6107 (6) Å,c= 16.422 (1) Å andV = 2213.8 (2) Å3. The crystal network contains O anion and Sr cation vacancies. The structure is complex, with Sr, Mo and O atoms distributed over four, two and six distinct Wyckoff sites, respectively. Only one of the Sr sites (SrO6) corresponds to the octahedral network; one of the two MoO6types of octahedra is axially distorted. The three other Sr positions occupy theAsite with higher coordination. There is an occupational deficit of O atoms of 22 (4)%. This defective framework material presents an interesting ionic mobility, enhanced above 773 K owing to a further reduction in the oxygen content.


2002 ◽  
Vol 239 (1-3) ◽  
pp. 164-166 ◽  
Author(s):  
R.S. Liu ◽  
T.S. Chan ◽  
S.F. Hu ◽  
J.G. Lin ◽  
C.Y. Huang

2020 ◽  
Vol 22 (5) ◽  
pp. 2986-2998 ◽  
Author(s):  
Vijay Khopkar ◽  
Balaram Sahoo

The microstructure and low-temperature dielectric properties of lead-free BaFe0.5Nb0.5O3 ceramics exhibiting a negative temperature coefficient of resistance behavior.


2020 ◽  
Vol 95 (11) ◽  
pp. 115704
Author(s):  
J L Rosas-Huerta ◽  
J E Antonio ◽  
M Romero ◽  
J León-Flores ◽  
J Pilo ◽  
...  

2005 ◽  
Vol 59 (18) ◽  
pp. 2296-2299 ◽  
Author(s):  
R. Shaheen ◽  
J. Bashir ◽  
H. Rundlöf ◽  
A.R. Rennie

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