Phase equilibria and thermodynamics of binary copper systems with 3d-metals. VII. Concentration-temperature dependences of the thermodynamic functions of mixing for liquid alloys of copper and transition metals

2007 ◽  
Vol 46 (11-12) ◽  
pp. 565-581 ◽  
Author(s):  
M. A. Turchanin
Keyword(s):  
Transition Metals ◽  
Phase Equilibria ◽  
Thermodynamic Functions ◽  
Liquid Alloys ◽  
3D Metals ◽  
Temperature Dependences

scholarly journals The Physical and Thermodynamic Functions of Borides

2017 ◽  
Vol 18 (1) ◽  
pp. 58-63
Author(s):  
N.Yu. Filonenko
Keyword(s):  
Free Energy ◽  
Physical Properties ◽  
Thermodynamic Functions ◽  
Point Of View ◽  
Energy Potential ◽  
High Temperature Expansion ◽  
Temperature Dependences ◽  
Function Calculation ◽  
First Time ◽  
Good Agreement

In the paper the physical properties and thermodynamic functions of borides Х2В (Х=W, Mo, Mn, Fe, Co, Ni та Cr) are studied with accounting for fluctuation processes. We use the microstructure analysis, the X-ray structural and the durometric analyses to determine the physical properties of alloys. In the paper it is determined the phase composition and physical properties of borides. In this paper for the first time it is determined the thermodynamic functions of borides using the Hillert and Staffansson model with accounting for the first degree approximation of high-temperature expansion for the free energy potential of binary alloys. We obtain the temperature dependences for such thermodynamic functions as Gibbs free energy, entropy, enthalpy and heat capacity Ср along with their values at the formation temperature for Х2В (Х=W, Mo, Mn, Fe, Co, Ni та Cr). The approach under consideration enables to give more thorough from the thermodynamic point of view description of borides formed from the liquid. The outcomes of the thermodynamic function calculation for borides are in good agreement with experimental data and results of other authors.

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