Alkali metal polyphosphides as intermediates in the synthesis of organophosphorus compounds from elemental phosphorus

2021 ◽  
Vol 70 (7) ◽  
pp. 1260-1268
Author(s):  
A. A. Zagidullin ◽  
A. V. Petrov ◽  
I. A. Bezkishko ◽  
V. A. Miluykov
Keyword(s):  
Alkali Metal ◽  
Organophosphorus Compounds ◽  
Elemental Phosphorus

ChemInform Abstract: Synthesis of Organophosphorus Compounds in Terms of Elemental Phosphorus, Sulfur and Their Derivatives

ChemInform ◽  
2010 ◽  
Vol 31 (10) ◽  
pp. no-no
Author(s):  
Elvira S. Batyeva ◽  
Il'Yas S. Nizamov ◽  
Lidiya I. Kursheva ◽  
Liliya V. Frolova
Keyword(s):  
Organophosphorus Compounds ◽  
Elemental Phosphorus

Elemental phosphorus–strong base as a system for the synthesis of organophosphorus compounds

1991 ◽  
Vol 60 (12) ◽  
pp. 1360-1367 ◽  
Author(s):  
Boris A Trofimov ◽  
T N Rakhmatulina ◽  
Nina K Gusarova ◽  
Svetlana F Malysheva
Keyword(s):  
Organophosphorus Compounds ◽  
Elemental Phosphorus ◽  
Strong Base

Synthesis of Organophosphorus Compounds in Terms of Elemental Phosphorus, Sulfur and their Derivatives

1999 ◽  
Vol 144 (1) ◽  
pp. 77-80 ◽  
Author(s):  
Elvira S. Batyeva ◽  
Il'yas S. Nizamov ◽  
Lidiya I. Kursheva ◽  
Liliya V. Frolova
Keyword(s):  
Organophosphorus Compounds ◽  
Elemental Phosphorus

Novel general halogen-free methodology for the synthesis of organophosphorus compounds

2012 ◽  
Vol 84 (3) ◽  
pp. 439-459 ◽  
Author(s):  
Nina K. Gusarova ◽  
Svetlana N. Arbuzova ◽  
Boris A. Trofimov
Keyword(s):  
Organophosphorus Compounds ◽  
Elemental Phosphorus ◽  
Phosphinic Acids ◽  
Halogen Free ◽  
Phosphine Chalcogenides

The use of novel general halogen-free methodology for the synthesis of phosphines, phosphine chalcogenides, and phosphinic acids from elemental phosphorus and alkenes and alkynes in the superbase suspensions is described.

scholarly journals Black Phosphorus: An Effective Feedstock for the Synthesis of Phosphorus-Based Chemicals

CCS Chemistry ◽  
2019 ◽  
Vol 1 (2) ◽  
pp. 166-172 ◽  
Author(s):  
Lie Wu ◽  
Shi Bian ◽  
Hao Huang ◽  
Jiahong Wang ◽  
Danni Liu ◽  
...  
Keyword(s):  
Organophosphorus Compounds ◽  
Black Phosphorus ◽  
White Phosphorus ◽  
The Novel ◽  
Phosphine Oxides ◽  
Elemental Phosphorus ◽  
One Pot ◽  
Mild Conditions ◽  
Novel Concept ◽  
Phosphine Sulfide

We propose and demonstrate the novel concept of synthesizing organophosphorus compounds directly from black phosphorus (BP) nanoparticles as the feedstock. Compounds such as alkyl phosphines, alkyl phosphine oxides, phosphine sulfide, and hexafluorophosphate anion are prepared with good isolation yields under mild conditions. Selective synthesis of primary, secondary, and tertiary organophosphorus compounds is also demonstrated utilizing this one-pot approach. Reaction mechanisms are proposed and discussed. Compared with traditional white phosphorus (P4)-based methods, the new synthetic concept and process utilizing elemental phosphorus are more efficient and environmentally friendly.

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