Surface oxygen vacancies boosted high rate performance of porous MnO2 anode for lithium-ion batteries

Ionics ◽  
2021 ◽  
Author(s):  
Xiaole Zhang ◽  
Song Li ◽  
Shenghe Wang ◽  
Kun Liu ◽  
Zining Zhang ◽  
...  
Processes ◽  
2021 ◽  
Vol 9 (9) ◽  
pp. 1655
Author(s):  
Yiguang Zhou ◽  
Shuhao Xiao ◽  
Zhenzhe Li ◽  
Xinyan Li ◽  
Jintao Liu ◽  
...  

Li4Ti5O12 (LTO), known as a zero-strain material, is widely studied as the anode material for lithium-ion batteries owing to its high safety and long cycling stability. However, its low electronic conductivity and Li diffusion coefficient significantly deteriorate its high-rate performance. In this work, we proposed a facile approach to introduce oxygen vacancies into the commercialized LTO via thermal treatment under Ar/H2 (5%). The oxygen vacancy-containing LTO demonstrates much better performance than the sample before H2 treatment, especially at high current rates. Density functional theory calculation results suggest that increasing oxygen vacancy concentration could enhance the electronic conductivity and lower the diffusion barrier of Li+, giving rise to a fast electrochemical kinetic process and thus improved high-rate performance.


RSC Advances ◽  
2016 ◽  
Vol 6 (49) ◽  
pp. 43551-43555 ◽  
Author(s):  
Mengmeng Zhen ◽  
Xiao Zhang ◽  
Lu Liu

Novel bi-component-active hierarchical ZnO/ZnCo2O4 nanosheets with mesostructures presented a good high-rate performance for lithium ion batteries.


2017 ◽  
Vol 52 (12) ◽  
pp. 7140-7148 ◽  
Author(s):  
Lijuan Wang ◽  
Xiaojie Wang ◽  
Zhaohui Meng ◽  
Hongjiang Hou ◽  
Baokuan Chen

2018 ◽  
Vol 212 ◽  
pp. 198-201 ◽  
Author(s):  
Xiaochuan Chen ◽  
Renpin Liu ◽  
Lingxing Zeng ◽  
Xiaoxia Huang ◽  
Yixing Fang ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (61) ◽  
pp. 49651-49656 ◽  
Author(s):  
Y. L. Wang ◽  
X. Huang ◽  
F. Li ◽  
J. S. Cao ◽  
S. H. Ye

Pristine LNCM and LNCMA as Li-rich cathode materials for lithium ion batteries were synthesized via a sol–gel route. The Al-substituted LNCM sample exhibits an enhanced high rate performance and superior cyclability.


Ionics ◽  
2021 ◽  
Author(s):  
Li Wang ◽  
Li Sheng ◽  
Jin Wang ◽  
Hong Xu ◽  
Guangyu Tian ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document