Lipase-catalyzed acidolysis of perilla oil with caprylic acid to produce structured lipids

2002 ◽  
Vol 79 (4) ◽  
pp. 363-367 ◽  
Author(s):  
In-Hwan Kim ◽  
Hakryul Kim ◽  
Ki-Teak Lee ◽  
Soo-Hyun Chung ◽  
Soon-Nam Ko
Keyword(s):  
Caprylic Acid ◽  
Structured Lipids ◽  
Perilla Oil

scholarly journals Oxidative Stability of Stripped Soybean Oil during Accelerated Oxidation: Impact of Monoglyceride and Triglyceride—Structured Lipids Using DHA as sn-2 Acyl-Site Donors

Foods ◽  
2019 ◽  
Vol 8 (9) ◽  
pp. 407
Author(s):  
Wang ◽  
Xie ◽  
Li ◽  
Miao ◽  
Wu
Keyword(s):  
Soybean Oil ◽  
Oxidative Stability ◽  
Induction Period ◽  
Caprylic Acid ◽  
Structured Lipids ◽  
Inhibitory Effect ◽  
Blank Group ◽  
Accelerated Oxidation ◽  
Oxidative Effects ◽  
Stripped Soybean Oil

The current work aimed to clarify the effects of four structured lipids, including monoglycerides with docosahexaenoic acid (2D-MAG), diacylglycerols with caprylic acid (1,3C-DAG), triglyceride with caprylic acid at sn-1,3 and DHA at sn-2 position (1,3C-2D-TAG) and caprylic triglyceride on the oxidative stability of stripped soybean oil (SSO). The results revealed that compared to the blank group of SSO, the oxidation induction period of the sample with 2 wt% 2D-MAG and that with 1,3C-DAG were delayed by 2–3 days under accelerated oxidation conditions (50 °C), indicating that 2D-MAG and 1,3C-DAG prolonged the oxidation induction period of SSO. However, the inhibitory effect of α-tocopherol on SSO oxidation was reduced by 2D-MAG after addition of 2D-MAG to SSO containing α-tocopherol. 2D-MAG exhibited different antioxidative/pro-oxidative effects in the added/non-added antioxidants system. Compared to caprylic triglyceride, DHA at the sn-2 acyl site induced oxidation of structured lipids, thus further promoting the oxidation of SSO. The antioxidant was able to inhibit not only the oxidation of DHA in the SSO, but also the transesterification of sn-2 DHA to sn-1/sn-3 DHA in the structured lipid.

Kinetics of lipase-catalysed interesterification of triolein and caprylic acid to produce structured lipids

2003 ◽  
Vol 78 (4) ◽  
pp. 461-470 ◽  
Author(s):  
B Camacho Paez ◽  
A Robles Medina ◽  
F Camacho Rubio ◽  
L Esteban Cerdán ◽  
E Molina Grima
Keyword(s):  
Caprylic Acid ◽  
Structured Lipids ◽  
Kinetics Of

Oxidative stability during storage of structured lipids produced from fish oil and caprylic acid

2004 ◽  
Vol 81 (4) ◽  
pp. 375-384 ◽  
Author(s):  
Nina Skall Nielsen ◽  
Xuebing Xu ◽  
Maike Timm-Heinrich ◽  
Charlotte Jacobsen
Keyword(s):  
Fish Oil ◽  
Oxidative Stability ◽  
Caprylic Acid ◽  
Structured Lipids

Enzymatic synthesis of high-purity structured lipids with caprylic acid at 1,3-positions and polyunsaturated fatty acid at 2-position

2001 ◽  
Vol 78 (6) ◽  
pp. 611-616 ◽  
Author(s):  
Akiko Kawashima ◽  
Yuji Shimada ◽  
Miwa Yamamoto ◽  
Akio Sugihara ◽  
Toshihiro Nagao ◽  
...  
Keyword(s):  
Fatty Acid ◽  
Polyunsaturated Fatty Acid ◽  
High Purity ◽  
Enzymatic Synthesis ◽  
Caprylic Acid ◽  
Structured Lipids

scholarly journals Incorporation of Caprylic Acid into a Docosahexaenoic Acid Single Cell Oil for the Production of Specialty Lipids

2020 ◽  
Vol 58 (4) ◽  
Author(s):  
Daniela Kanno Mathias ◽  
Jacqueline Piazentin Costa ◽  
Carolina Rodrigues Calvo ◽  
Roberta Roerta Claro da Silva ◽  
Attilio Converti ◽  
...  
Keyword(s):  
Docosahexaenoic Acid ◽  
Single Cell ◽  
Caprylic Acid ◽  
Experimental Approach ◽  
Structured Lipids ◽  
Novozym 435 ◽  
Molar Ratio ◽  
Single Cell Oil ◽  
Lipozyme Tl Im ◽  
Scientific Contribution

Research background. New sources of docosahexaenoic acid have recently been investigated aiming at infant formula fortification and dietary supplementation, among which the docosahexaenoic acid single cell oil, which contains 40-50 % of this acid. Experimental approach. For this purpose, such an oil was blended with caprylic acid in molar proportions ranging from 1:1 to 5:1 and the blends were interesterified using either Novozym 435 or Lipozyme TL IM as the catalyst. The influence of the amount of excess free caprylic acid in the substrate, as well as the type of enzyme on the triacylglycerol rearrangement resulting from the synthesis of the structured lipids were evaluated. Results and conclusions. The regiospecific lipase Lipozyme TL IM seemed to induce transesterification among single cell oil triacylglycerols preferably to acidolysis with caprylic acid, which was directly proportional to the ratio of this acid in the substrate. In reactions catalyzed by the non-regiospecific lipase Novozym 435, a higher incorporation of caprylic acid by single cell oil triacylglycerols was observed when compared with Lipozyme TL IM, independently of the oil:caprylic acid molar ratio. Novelty and scientific contribution. These results revealed the importance of combining the choice of the type of lipase, either regiospecific or not, with the proportions of excess free fatty acids in acidolysis reactions when aiming to produce structured lipids as a source of docosahexaenoic acid.

LIPASE-CATALYZED PRODUCTION OF STRUCTURED LIPIDS VIA ACIDOLYSIS OF FISH OIL WITH CAPRYLIC ACID

2007 ◽  
Vol 7 (4) ◽  
pp. 263-274 ◽  
Author(s):  
DEQUAN ZHOU ◽  
XUEBING XU ◽  
HUILING MU ◽  
CARL-ERIK HØY ◽  
JENS ADLER-NISSEN
Keyword(s):  
Fish Oil ◽  
Caprylic Acid ◽  
Structured Lipids
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