scholarly journals Synergistic dynamics of photoionization and photoinduced electron transfer probed by laser flash photolysis and ultrafast fluorescence spectroscopy

2021 ◽  
Vol 20 (9) ◽  
pp. 1109-1124
Author(s):  
Namasivayam Dhenadhayalan ◽  
Angel Shaji Veeranepolian Selvi ◽  
Selvaraju Chellappan ◽  
Viruthachalam Thiagarajan
Keyword(s):  
Electron Transfer ◽  
Fluorescence Spectroscopy ◽  
Photoinduced Electron Transfer ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash

Photoinduced electron transfer C—C bond cleavage reactions; oxidations and isomerizations

1984 ◽  
Vol 62 (3) ◽  
pp. 424-436 ◽  
Author(s):  
L. W. Reichel ◽  
G. W. Griffin ◽  
A. J. Muller ◽  
P. K. Das ◽  
Seyhan N. Ege
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Bond Cleavage ◽  
Radical Cations ◽  
Laser Flash ◽  
Time Resolved ◽  
Fragmentation Reactions ◽  
Oxidative Products

We have shown that radical cations generated by photoinduced electron transfer (ET) in 1,2-diarylethanes, aryl pinacols, and their derivatives undergo fragmentation reactions. In the presence of oxygen oxidative products are obtained. Time-resolved laser flash photolysis and other ancillary techniques have permitted us to define the mechanisms of certain oxidative processes observed.

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