Laser photolysis/laser-induced fluorescence study of the reaction of hydroxyl radical with ethylene

1983 ◽  
Vol 96 (2) ◽  
pp. 148-153 ◽  
Author(s):  
Frank P. Tully
Keyword(s):  
Hydroxyl Radical ◽  
Laser Induced Fluorescence ◽  
Laser Photolysis ◽  
Fluorescence Study ◽  
Photolysis Laser

Kinetics of gas-phase tropospheric reactions of organic solvents and hydroxyl radical by laser photolysis laser-induced fluorescence

1998 ◽  
Author(s):  
Michael Kompitsas ◽  
A. Mellouki ◽  
Georges Le Bras ◽  
F. Roubani-Kalantzopoulou ◽  
A. Mavropoulos ◽  
...  
Keyword(s):  
Hydroxyl Radical ◽  
Gas Phase ◽  
Organic Solvents ◽  
Laser Induced Fluorescence ◽  
Laser Photolysis ◽  
Photolysis Laser ◽  
Kinetics Of

scholarly journals A Time Resolved IR Laser Photolysis-Laser Induced Fluorescence Study of the OH/Methanol Reaction

1995 ◽  
Vol 16 (2) ◽  
pp. 53-61
Author(s):  
José M. Riveros ◽  
Luis Gilberto Barreta
Keyword(s):  
Isotope Effects ◽  
Laser Induced Fluorescence ◽  
Bulk Temperature ◽  
Buffer Gas ◽  
Fluorescence Study ◽  
Time Resolved ◽  
Ir Laser ◽  
Multiphoton Dissociation ◽  
Photolysis Laser ◽  
Good Agreement

The reaction of hydroxyl radicals (OH and OD) generated by infrared multiphoton dissociation of different isotopomers of methanol were studied in the presence of variable amounts of Ar buffer gas. The disappearance of the OH, or OD, radicals in the presence of the parent methanol was followed by laser induced fluorescence at 310 nm. Comparison of the rate constants obtained from these experiments reveal good agreement with observed isotope effects observed by other authors but suggest that the reactions occurs at higher temperatures than the macroscopic bulk temperature of the sample.

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