Temperature and Pressure Dependent Rate Coefficients for the Reaction of Hg with Cl and the Reaction of Cl with Cl:  A Pulsed Laser Photolysis−Pulsed Laser Induced Fluorescence Study

2005 ◽  
Vol 109 (34) ◽  
pp. 7732-7741 ◽  
Author(s):  
Deanna L. Donohoue ◽  
Dieter Bauer ◽  
Anthony J. Hynes
Keyword(s):  
Pulsed Laser ◽  
Laser Induced Fluorescence ◽  
Laser Photolysis ◽  
Rate Coefficients ◽  
Fluorescence Study ◽  
Dependent Rate ◽  
Temperature And Pressure

Pulsed-laser photolysis of Mn2(CO)10: A time-resolved fluorescence study

1996 ◽  
Vol 62 (2) ◽  
pp. 169-171
Author(s):  
P. Kub�t ◽  
J. Krh�t ◽  
T. Vondr�k ◽  
Z. Zelinger
Keyword(s):  
Pulsed Laser ◽  
Laser Photolysis ◽  
Time Resolved Fluorescence ◽  
Fluorescence Study ◽  
Time Resolved

Reaction of Hydroxyl Radicals with C4H5N (Pyrrole): Temperature and Pressure Dependent Rate Coefficients

2012 ◽  
Vol 116 (24) ◽  
pp. 6051-6058 ◽  
Author(s):  
Terry J. Dillon ◽  
Maria E. Tucceri ◽  
Katrin Dulitz ◽  
Abraham Horowitz ◽  
Luc Vereecken ◽  
...  
Keyword(s):  
Hydroxyl Radicals ◽  
Rate Coefficients ◽  
Dependent Rate ◽  
Temperature And Pressure

Excimer Laser Photolysis of Organometallic Compounds Adsorbed on Substrates

1987 ◽  
Vol 101 ◽  
Author(s):  
Hideyuki Suzuki ◽  
Koji Mori ◽  
Masahiro Kawasaki ◽  
Hiroyasu Sato
Keyword(s):  
Excimer Laser ◽  
Organometallic Compounds ◽  
Laser Induced Fluorescence ◽  
Laser Photolysis ◽  
Excitation Wavelength ◽  
Temperature And Pressure

ABSTRACTExcimer laser photolysis at 248 nm of trimethylgal1ium (TMG) was studied by probing gallium atoms by laser induced fluorescence (LIF) technique. From the dependence of LIF intensity on the excitation wavelength, temperature and pressure, a thermally assisted photodissociation in the chemisorbed state was concluded.

scholarly journals Temperature-(208–318 K) and pressure-(18–696 Torr) dependent rate coefficients for the reaction between OH and HNO<sub>3</sub>

2018 ◽  
Vol 18 (4) ◽  
pp. 2381-2394 ◽  
Author(s):  
Katrin Dulitz ◽  
Damien Amedro ◽  
Terry J. Dillon ◽  
Andrea Pozzer ◽  
John N. Crowley
Keyword(s):  
Cross Sections ◽  
Pressure Dependence ◽  
Low Temperatures ◽  
Room Temperature ◽  
Rate Coefficients ◽  
Title Reaction ◽  
Data Set ◽  
Dependent Rate ◽  
Temperature And Pressure

Abstract. Rate coefficients (k5) for the title reaction were obtained using pulsed laser photolytic generation of OH coupled to its detection by laser-induced fluorescence (PLP–LIF). More than 80 determinations of k5 were carried out in nitrogen or air bath gas at various temperatures and pressures. The accuracy of the rate coefficients obtained was enhanced by in situ measurement of the concentrations of both HNO3 reactant and NO2 impurity. The rate coefficients show both temperature and pressure dependence with a rapid increase in k5 at low temperatures. The pressure dependence was weak at room temperature but increased significantly at low temperatures. The entire data set was combined with selected literature values of k5 and parameterised using a combination of pressure-dependent and -independent terms to give an expression that covers the relevant pressure and temperature range for the atmosphere. A global model, using the new parameterisation for k5 rather than those presently accepted, indicated small but significant latitude- and altitude-dependent changes in the HNO3 ∕ NOx ratio of between −6 and +6 %. Effective HNO3 absorption cross sections (184.95 and 213.86 nm, units of cm2 molecule−1) were obtained as part of this work: σ213.86  =  4.52−0.12+0.23  ×  10−19 and σ184.95  =  1.61−0.04+0.08  ×  10−17.

Kinetic Analysis of Complex Chemical Activation and Unimolecular Dissociation Reactions using QRRK Theory and the Modified Strong Collision Approximation

2000 ◽  
Vol 214 (11) ◽  
Author(s):  
A.Y. Chang ◽  
J.W. Bozzelli ◽  
A.M. Dean
Keyword(s):  
Chemical Activation ◽  
Peroxy Radical ◽  
Dissociation Rate ◽  
Rate Coefficients ◽  
Unimolecular Dissociation ◽  
Frequency Model ◽  
Dependent Rate ◽  
Vinyl Radical ◽  
Temperature And Pressure ◽  
Collision Approximation

A method to predict temperature and pressure-dependent rate coefficients for complex bimolecular chemical activation and unimolecular dissociation reactions is described. A three-frequency version of QRRK theory is developed and collisional stabilization is estimated using the modified strong-collision approximation. The methodology permits analysis of reaction systems with an arbitrary degree of complexity in terms of the number of isomer or product channels. Specification of both high and low pressure limits is also provided. The chemically activated reaction of vinyl radical with molecular oxygen is used to demonstrate the approach. Subsequent dissociation of the stabilized vinyl peroxy radical is used to illustrate prediction of dissociation rate coefficients. These calculations confirm earlier results that the vinoxy + O channel is dominant under combustion conditions. The results are also consistent with RRKM results using the same input conditions. This approach provides a means to provide reasonably accurate predictions of the rate coefficients that are required in many detailed mechanisms. The major advantage is the ability to provide reasonable estimates of rate coefficients for many complex systems where detailed information about the transition states is not available. It is also shown that a simpler 1-frequency model appears adequate for high temperature conditions.

Temperature and Pressure-Dependent Rate Coefficients for the Reaction of Vinyl Radical with Molecular Oxygen

2015 ◽  
Vol 119 (28) ◽  
pp. 7766-7779 ◽  
Author(s):  
C. Franklin Goldsmith ◽  
Lawrence B. Harding ◽  
Yuri Georgievskii ◽  
James A. Miller ◽  
Stephen J. Klippenstein
Keyword(s):  
Molecular Oxygen ◽  
Rate Coefficients ◽  
Dependent Rate ◽  
Vinyl Radical ◽  
Temperature And Pressure
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