Surface and dynamical properties of GeI2

GeI2 is an interesting two-dimensional (2D) wide-band gap semiconductor because of diminished edge scattering due to an absence of dangling bonds. Angle-resolved x-ray photoemission spectroscopy (ARXPS) indicates a germanium rich surface, and a surface to bulk core-level shift of 1.8 eV in binding energy, between the surface and bulk components of the Ge 2p3/2 core-level, making clear that the surface is different from the bulk. Temperature dependent studies indicate an effective Debye temperature (θD ) of 186 ± 18 K for the germanium x-ray photoemission spectroscopy (XPS) feature associated with the surface. These measurements also suggest an unusually high effective Debye temperature for iodine (587 ± 31 K), implying that iodine is present in the bulk of the material, and not the surface. From optical absorbance, GeI2 is seen to have an indirect (direct) optical band gap of 2.60 (2.8) ± 0.02 (0.1) eV, consistent with the expectations. Temperature dependent magnetometry indicates that GeI2 is moment paramagnetic at low temperatures (close to 4 K) and shows a diminishing saturation moment at high temperatures (close to 300 K and above).

Synergistic effects of iron and hexagonal-Boron Nitride additions in copper-based composites for braking application

This paper explores the addition of h-BN and iron to Cu-based brake pads on the performance benefits. It also investigates the effect of graded layering by synthesizing three and four-layer brake pads by powder compaction and sintering route. The top one or two layers are made of Cu-based composite containing Fe, h-BN, and W, while the middle layer is pure Cu and, bottom steel plate. Two different compositions were explored for the composites by varying Fe content. From the two composite compositions, brake pads with single-layer composite or two-layer composite were synthesized. Characterization of brake pad specimens was carried out using density measurements, optical microscopy, scanning electron microscopy, energy dispersive spectroscopy. The brake pads were subjected to simulated braking tests at braking energy/cycle of 60, 96, and 136 K Joules. Wear rate, coefficient of friction, stopping distance, stopping time, and hardness were measured and compared among other brake pads. The brake pad containing single-layer Fe rich Cu composite showed the best performance in the simulated braking tests. EDS analysis of wear debris shows the formation of iron (boride, nitride, oxide) complex which is indicative of a surface with superior dry lubricating properties. This surface is a result of synergetic interaction between h-BN and Fe particles. The iron particles which are scattered in the Cu matrix composite act as low friction regions on the brake pad surface that interrupt the high friction regions on the Cu matrix, thus reducing the local and bulk temperature rise. The two-layer composite brake-pad showed performance intermediate to the two single-layer brake pads. No advantage due to higher thermal conductivities in Fe deficient composite was observed as the two composite layers, showed similar Fe contents in their matrix phases.

Retrieving Equivalent Shear Viscosity for Molten Polymers from 3-D Nonisothermal Capillary Flow Simulation

For highly viscous polymer melts, considerable fluid temperature rises produced by viscous heating can be a disturbing factor in viscosity measurements. By scrutinizing the experimental and simulated capillary pressure losses for polymeric liquids, we demonstrate the importance of applying a viscous heating correction to the shear viscosity, so as to correct for large errors introduced by the undesirable temperature rises. Specifically, on the basis of a theoretical derivation and 3-D nonisothermal flow simulation, an approach is developed for retrieving the equivalent shear viscosity in capillary rheometry, and we show that the shear viscosity can be evaluated by using the average fluid temperature at the wall, instead of the bulk temperature, as previously assumed. With the help of a viscous Cross model in analyzing the shear-dominated capillary flow, it is possible to extract the viscous heating contribution to capillary pressure loss, and the general validity of the methodology is assessed using the experiments on a series of thermoplastic melts, including polymers of amorphous, crystalline, and filler-reinforced types. The predictions of the viscous model based on the equivalent viscosity are found to be in good to excellent agreement with experimental pressure drops. For all the materials studied, a near material-independent scaling relation between the dimensionless temperature rise (Θ) and the Nahme number (Na) is found, Θ ~ Na0.72, from which the fluid temperature rise due to viscous heating as well as the resultant viscosity change can be predicted.

A Bayesian data assimilation framework for lake 3D hydrodynamic models with a physics-preserving particle filtering method using SPUX-MITgcm v1

We present a Bayesian inference for a three-dimensional hydrodynamic model of Lake Geneva with stochastic weather forcing and high-frequency observational datasets. This is achieved by coupling a Bayesian inference package, SPUX, with a hydrodynamics package, MITgcm, into a single framework, SPUX-MITgcm. To mitigate uncertainty in the atmospheric forcing, we use a smoothed particle Markov chain Monte Carlo method, where the intermediate model state posteriors are resampled in accordance with their respective observational likelihoods. To improve the assimilation of remotely sensed temperature, we develop a bi-directional Long Short-Term Memory (Bi-LSTM) neural network to estimate lake skin temperature from a history of hydrodynamic bulk temperature predictions and atmospheric data. This study analyzes the benefit and costs of such state of the art computationally expensive calibration and assimilation method for lakes.

Effects of radius ratio on annular centrifugal Rayleigh–Bénard convection

We report on a three-dimensional direct numerical simulation study of flow structure and heat transport in the annular centrifugal Rayleigh–Bénard convection (ACRBC) system, with cold inner and hot outer cylinders corotating axially, for the Rayleigh number range $Ra \in [{10^6},{10^8}]$ and radius ratio range $\eta = {R_i}/{R_o} \in [0.3,0.9]$ ( $R_i$ and $R_o$ are the radius of the inner and outer cylinders, respectively). This study focuses on the dependence of flow dynamics, heat transport and asymmetric mean temperature fields on the radius ratio $\eta$ . For the inverse Rossby number $Ro^{-1} = 1$ , as the Coriolis force balances inertial force, the flow is in the inertial regime. The mechanisms of zonal flow revolving in the prograde direction in this regime are attributed to the asymmetric movements of plumes and the different curvatures of the cylinders. The number of roll pairs is smaller than the circular roll hypothesis as the convection rolls are probably elongated by zonal flow. The physical mechanism of zonal flow is verified by the dependence of the drift frequency of the large-scale circulation (LSC) rolls and the space- and time-averaged azimuthal velocity on $\eta$ . The larger $\eta$ is, the weaker the zonal flow becomes. We show that the heat transport efficiency increases with $\eta$ . It is also found that the bulk temperature deviates from the arithmetic mean temperature and the deviation increases as $\eta$ decreases. This effect can be explained by a simple model that accounts for the curvature effects and the radially dependent centrifugal force in ACRBC.

Analysis of parallel flow heat exchanger using SiO2 nanofluids in the laminar flow region

Convective and overall heat transfer coefficients of SiO2 nanofluid flowing in a concentric DTHE are determined experimentally. The tests are carried out in the 800<Re<1900 range using SiO2/22nm nanofluids prepared in 0.2, 0.6 and 1.0% volume concentrations in 30:70 ratio glycerol-water mixture base liquid. The thermal and physical properties of silica nanofluids are determined in the range of 20-80°C. Viscosity, thermal conductivity, and density of nanofluids increased with particle concentration whereas specific heat decreased. Thermal conductivity and specific heat of nanofluids increased with temperature while viscosity and density decreased. Heat transfer experiments are conducted using nanofluids at a bulk temperature of 35°C in a laminar developing flow region. Overall heat transfer coefficient and convective HTC of 1.0% silica nanofluids are increased by 21.2 and 36.3% compared to base liquid.

On the interest of a semi-empirical model for the tooth friction coefficient in gear transmissions

Accurate modelling of friction coefficient is of primary importance in efficiency, vibration and failure analyses of enclosed gear drives. After showing the influence of surface/lubricant interactions on friction, the authors used a semi-empirical model which can take all these aspects into account. Lubricant is modelled as an Eyring–Reynolds fluid and rough surfaces are described with two parameters via a stochastic approach. A specific two-disc machine is used to perform series of friction measurements on smooth and rough discs. Smooth discs allow to operate under full film lubrication and to measure a reference shear stress of lubricant, whereas rough discs reproduce gear tooth roughness and generate a representative value of friction on asperities. The purpose of this present paper is to describe calculations of this physical-based friction coefficient model and to present the experimental process. On the basis of new results, the impact of a surface finishing process is assessed as well as the consequence of calculating friction coefficient based on oil injection instead of local bulk temperature.

Performance Analysis and Quality Evaluation of Wheat Storage in Horizontal Silo Bags

Wheat still suffers from the problem of traditional storage methods, limited storage capacity, and a high percentage of losses in terms of quantity and quality. Hermetic silo bags are economical and alternative technique to the traditional storage methods. Ten horizontal plastic silos with the capacity of 200 tons/silo were tested and evaluated for eight months of wheat storage. The evaluations included grain bulk temperature, CO2 concentration, fungal and microbial count, insect count, grain moisture content, 1000-grain weight, falling number, and protein content. The results showed that the stored wheat quality was maintained without any significant difference during the storage period in terms of 1000-grain weight, grain moisture content, and falling number, while there were slight changes in protein content and kernel hardness with a decrease of 5.5% and 4.6% at the end of the storage period. There were no statistically significant differences at the sampling location along the length of the storage silos, which confirms the homogeneity of the internal conditions of the examined silo. The grain bulk temperature inside the silos was always lower than the surrounding ambient air temperature. The higher concentration of carbon dioxide inside the silos during the storage period led to a decrease in fungal and microbial count and the presence of dead insects at the end of the storage period.

Determination of Limiting Heat Flux for The Inception of Nucleate Boiling Regime for Crude Oils

Finding the limiting heat flux above which nucleate boiling starts and below which forced convective heat transfer exists is a crucial task for the accuracy of results from crude oil fouling tests. In this study, crude oils from two sources were tested at bulk temperatures of 100, 120 and 140 °C and different velocities. Heat transfer coefficient increased gradually with bulk temperature indicated lowering of the viscosity at high temperatures which promoted turbulence and enhanced heat transfer. The velocity effects were similar to that of bulk temperatures on maximum heat transfer coefficient while less heat flux was required to achieve the same surface temperature at lower velocities. Deshannavar and Ramasamy’s model to predict maximum heat flux was compared with experimental results and a poor estimation was observed for the crude oils tested.