Photochemical isomerization in the absence of a potential barrier: origin of wavelength-dependent ground-state recovery kinetics

1991 ◽  
Vol 185 (5-6) ◽  
pp. 461-467 ◽  
Author(s):  
Ulf Åberg ◽  
Villy Sundström
Keyword(s):  
Potential Barrier ◽  
Ground State ◽  
State Recovery ◽  
Photochemical Isomerization

Photochemical isomerization in the absence of a potential barrier

1986 ◽  
Vol 126 (5) ◽  
pp. 385-393 ◽  
Author(s):  
Eva Åkesson ◽  
Hans Bergström ◽  
Villy Sundström ◽  
Tomas Gillbro
Keyword(s):  
Potential Barrier ◽  
Photochemical Isomerization

Solvent dependence of the ultrafast ground state recovery dynamics of phenol blue

2001 ◽  
Vol 90 (1-3) ◽  
pp. 295-302 ◽  
Author(s):  
Yutaka Nagasawa ◽  
Ayako Watanabe ◽  
Yoshito Ando ◽  
Tadashi Okada
Keyword(s):  
Ground State ◽  
State Recovery ◽  
Solvent Dependence ◽  
Phenol Blue ◽  
Recovery Dynamics

scholarly journals Determination of a High Potential Barrier Hindering Internal Rotation from the Ground State Spectrum

1983 ◽  
Vol 38 (9) ◽  
pp. 1010-1014 ◽  
Author(s):  
W. Stahl ◽  
H. Dreizler ◽  
M. Hayashi
Keyword(s):  
Internal Rotation ◽  
Potential Barrier ◽  
Ground State ◽  
High Potential ◽  
Rotational Spectrum ◽  
High Potential Barrier

Abstract We present an analysis of the rotational spectrum of ethylchloride-35Cl in the ground state. The 35Cl-hfs analysis was extended and the barrier to internal rotation determined from narrow splittings of high J-transitions.

Femtosecond ground state recovery: Measuring the intersystem crossing yield of polyspirobifluorene

2006 ◽  
Vol 124 (23) ◽  
pp. 234903 ◽  
Author(s):  
S. M. King ◽  
C. Rothe ◽  
D. Dai ◽  
A. P. Monkman
Keyword(s):  
Ground State ◽  
Intersystem Crossing ◽  
State Recovery

Photochemical isomerization in the absence of a potential barrier

1991 ◽  
Vol 103 (3) ◽  
pp. 441-446
Author(s):  
Ulf Åberg ◽  
Villy Sundström
Keyword(s):  
Potential Barrier ◽  
Photochemical Isomerization

scholarly journals The influence of the FeCp(CO)2+moiety on the dynamics of the metalloid [Ge9(Si(SiMe3)3)3]−cluster in thf: synthesis and characterization by time-resolved absorption spectroscopy

2019 ◽  
Vol 48 (41) ◽  
pp. 15577-15582 ◽  
Author(s):  
Nadine C. Michenfelder ◽  
Christian Gienger ◽  
Andreas Schnepf ◽  
Andreas-Neil Unterreiner
Keyword(s):  
Transition Metal ◽  
Absorption Spectroscopy ◽  
Ground State ◽  
Strong Influence ◽  
Synthesis And Characterization ◽  
Time Resolved ◽  
State Recovery ◽  
Covalently Bound

Photoexcitation of a newly synthesized, neutral tetrasubstituted Ge9cluster with a covalently bound transition metal substituent led to a complete ground state recovery within 150 ps indicating the strong influence of the Fe moiety.

Determination of a High Potential Barrier Hindering Internal Rotation from the Ground State Spectrum. The Methylbarrier of Ethylbromide

1985 ◽  
Vol 40 (6) ◽  
pp. 575-587 ◽  
Author(s):  
J. Gripp ◽  
H. Dreizler ◽  
R. Schwarz
Keyword(s):  
Hyperfine Structure ◽  
Internal Rotation ◽  
Potential Barrier ◽  
Ground State ◽  
Rotational Spectrum ◽  
Centrifugal Distortion ◽  
Vibrational Ground State ◽  
Distortion Analysis ◽  
High Potential Barrier

For ethylbromide a determination of the parameters of internal rotation is given derived from the rotational spectrum of the torsional and vibrational ground state. The Br-hyperfine structure is reanalysed with higher precision. As high J transitions were measured a centrifugal distortion analysis was necessary.

Picosecond ground state recovery of the F-center in RbCl, KCl and KBr

1991 ◽  
Vol 119-121 (1) ◽  
pp. 369-374
Author(s):  
Jan De Kinder ◽  
Wim Joosen ◽  
Dirk Schoemaker**
Keyword(s):  
Ground State ◽  
State Recovery ◽  
F Center
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