Chemical reactivity from the vibrational ground-state level. The role of the tunneling path in the tautomerization of urea and derivatives

Recent developments of low-temperature techniques are providing valuable knowledge about chemical processes that manifest in the quantum regimen.

Population inversion in laser-driven N2+

The time-dependent population transfer process of N2+ generated in an intense laser pulse has been investigated using the quasi-stationary Floquet theory by assuming that N2+ experiences an intense laser pulse with the sudden turn-on. A light-dressed B state is formed with a significant amount of population when pulse is suddenly turned on and is adiabatically transformed to the vibrational ground state (v = 0) of the field-free B state when the pulse vanishes. In addition, a part of the population is transferred to the electronically excited A state through one-photon resonance, which also contributes to decreasing the final population in the X state, facilitating the population inversion between the B state and the X state.

Structural investigation of neutron-deficient Pt isotopes: the case of 178Pt

Lifetime measurements with the recoil distance Doppler-shift technique have been performed to determine yrast E2 transition strengths in 178Pt. The experimental data are related to those on neighboring Pt isotopes, especially recent data on 180Pt, and compared to calculations within the interacting boson model and a Hartree-Fock Bogoliubov approach. These models predict prolate deformed ground states in Pt isotopes close to neutron midshell consistent with the experimental findings. Further, evidence was found that the prolate intruder structure observed in neutron-deficient Hg isotopes that is minimum in energy in 182Hg becomes the ground state configuration in 178Pt and neighboring 180Pt with nearly identical transition quadrupole moments. The new data on 178Pt are further discussed in the context of the systematics along the Pt isotopic chain with respect to a possible sharp shape transition towards a weakly deformed or a quasi-vibrational ground state whereas the prolate structure increases in energy in 174,176Pt and becomes an intruder configuration similar to, for example, 180,182Hg.