Application of transient response techniques for quantitative determination of adsorbed carbon monoxide and carbon present on the surface of a ruthenium catalyst during Fischer-Tropsch synthesis

Journal of Catalysis ◽

10.1016/0021-9517(84)90357-9 ◽

1984 ◽

Vol 86 (1) ◽

pp. 158-172 ◽

Author(s):

P WINSLOW

Keyword(s):

Carbon Monoxide ◽

Quantitative Determination ◽

Transient Response ◽

Ruthenium Catalyst ◽

Tropsch Synthesis ◽

Fischer Tropsch ◽

Fischer Tropsch Synthesis ◽

Adsorbed Carbon

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A quantitative determination of reaction mechanisms from density functional theory calculations: Fischer–Tropsch synthesis on flat and stepped cobalt surfaces

Journal of Catalysis ◽

10.1016/j.jcat.2008.01.009 ◽

2008 ◽

Vol 254 (2) ◽

pp. 285-295 ◽

Author(s):

J CHENG ◽

X GONG ◽

P HU ◽

C LOK ◽

P ELLIS ◽

...

Keyword(s):

Density Functional Theory ◽

Quantitative Determination ◽

Reaction Mechanisms ◽

Density Functional ◽

Density Functional Theory Calculations ◽

Tropsch Synthesis ◽

Fischer Tropsch ◽

Functional Theory ◽

Fischer Tropsch Synthesis

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Quantitative Determination of C–C Coupling Mechanisms and Detailed Analyses on the Activity and Selectivity for Fischer–Tropsch Synthesis on Co(0001): Microkinetic Modeling with Coverage Effects

ACS Catalysis ◽

10.1021/acscatal.9b01150 ◽

2019 ◽

Vol 9 (7) ◽

pp. 5957-5973 ◽

Author(s):

Zihao Yao ◽

Chenxi Guo ◽

Yu Mao ◽

P. Hu

Keyword(s):

Quantitative Determination ◽

Tropsch Synthesis ◽

Microkinetic Modeling ◽

Fischer Tropsch ◽

Fischer Tropsch Synthesis ◽

Coverage Effects ◽

Coupling Mechanisms

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95/01271 Spectroscopic studies of the determination of chain growth intermediate in the Fischer Tropsch synthesis reaction on the bimetallic supported system

Fuel and Energy Abstracts ◽

10.1016/0140-6701(95)92936-3 ◽

1995 ◽

Vol 36 (2) ◽

pp. 90

Keyword(s):

Spectroscopic Studies ◽

Tropsch Synthesis ◽

Chain Growth ◽

Synthesis Reaction ◽

Fischer Tropsch ◽

Fischer Tropsch Synthesis

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On the effect of water during Fischer–Tropsch synthesis with a ruthenium catalyst

Catalysis Today ◽

10.1016/s0920-5861(01)00469-2 ◽

2002 ◽

Vol 71 (3-4) ◽

pp. 419-427 ◽

Author(s):

Michael Claeys ◽

Eric van Steen

Keyword(s):

Ruthenium Catalyst ◽

Tropsch Synthesis ◽

Fischer Tropsch ◽

Fischer Tropsch Synthesis ◽

Effect Of Water

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Fe/Mn Oxide Catalysts for Fischer-Tropsch-Synthesis Part VII: Adsorption of Carbon Monoxide and Nitrogen at Low Temperatures

Berichte der Bunsengesellschaft für physikalische Chemie ◽

10.1002/bbpc.19860901222 ◽

1986 ◽

Vol 90 (12) ◽

pp. 1234-1238 ◽

Author(s):

D. Hess ◽

H. Papp ◽

M. Baerns

Keyword(s):

Carbon Monoxide ◽

Low Temperatures ◽

Oxide Catalysts ◽

Tropsch Synthesis ◽

Fischer Tropsch ◽

Fischer Tropsch Synthesis ◽

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The fischer-tropsch synthesis over a ruthenium catalyst under composition cycling

The Canadian Journal of Chemical Engineering ◽

10.1002/cjce.5450650611 ◽

1987 ◽

Vol 65 (6) ◽

pp. 958-965 ◽

Author(s):

Gerald S. Ross ◽

R. R. Hudgins ◽

P. L. Silveston

Keyword(s):

Ruthenium Catalyst ◽

Tropsch Synthesis ◽

Fischer Tropsch ◽

Fischer Tropsch Synthesis

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Carbon Monoxide Activation on Cobalt Carbide for Fischer–Tropsch Synthesis from First-Principles Theory

ACS Catalysis ◽

10.1021/acscatal.9b00649 ◽

2019 ◽

Vol 9 (9) ◽

pp. 8093-8103 ◽

Author(s):

Pei-Pei Chen ◽

Jin-Xun Liu ◽

Wei-Xue Li

Keyword(s):

Carbon Monoxide ◽

First Principles ◽

Tropsch Synthesis ◽

Fischer Tropsch ◽

Fischer Tropsch Synthesis ◽

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Kinetic Measurements of the Hydrogenation of Carbon Monoxide (Fischer-Tropsch Synthesis) Using an Internal Recycle Reactor

ACS Symposium Series - Chemical Reaction Engineering—Houston ◽

10.1021/bk-1978-0065.ch003 ◽

1978 ◽

pp. 26-36 ◽

Author(s):

A. ZEIN EL DEEN ◽

J. JACOBS ◽

M. BAERNS

Keyword(s):

Carbon Monoxide ◽

Tropsch Synthesis ◽

Fischer Tropsch ◽

Kinetic Measurements ◽

Fischer Tropsch Synthesis ◽

Recycle Reactor ◽

Hydrogenation Of Carbon Monoxide

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Mechanistic Aspects of the Activation of Silica-Supported Iron Catalysts for Fischer-Tropsch Synthesis in Carbon Monoxide and Syngas

ChemCatChem ◽

10.1002/cctc.201500811 ◽

2015 ◽

Vol 8 (2) ◽

pp. 390-395 ◽

Author(s):

P. A. Chernavskii ◽

V. O. Kazak ◽

G. V. Pankina ◽

V. V. Ordomsky ◽

A. Y. Khodakov

Keyword(s):

Carbon Monoxide ◽

Tropsch Synthesis ◽

Iron Catalysts ◽

Fischer Tropsch ◽

Fischer Tropsch Synthesis ◽

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Fischer-Tropsch CO-Hydrogenation on SiO2-supported Osmium Complexes

Zeitschrift für Naturforschung B ◽

10.1515/znb-2008-0311 ◽

2008 ◽

Vol 63 (3) ◽

pp. 289-292 ◽

Author(s):

Ntombovuyo Bungane ◽

Cathrin Welker ◽

Eric van Steen ◽

Michael Claeys

Keyword(s):

Carbon Monoxide ◽

Co Hydrogenation ◽

Bond Formation ◽

Organometallic Complexes ◽

Tropsch Synthesis ◽

Fischer Tropsch ◽

Fischer Tropsch Synthesis ◽

High Olefin ◽

Osmium Complexes ◽

The conversion of carbon monoxide with hydrogen was studied on a standard Os on SiO2 catalyst at different reaction temperatures, in the range between 200 and 300 °C. Additionally, supported di- and triatomic organometallic Os complexes were tested for their activity in the Fischer-Tropsch synthesis at 220 °C. All compounds showed formation of hydrocarbons, indicating that the organoosmium complexes are indeed active for C─C bond formation. Osmium as Fischer-Tropsch catalyst, however, is approximately 100 times less active compared to ruthenium. Very high methane selectivities (> 90 C-%) were obtained as well as high olefin to paraffin ratios, in particular with the organometallic complexes tested.

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