Thermodynamic properties of binary liquid alloys of silver with rare earth metals

1987 ◽  
Vol 133 (2) ◽  
pp. 181-192 ◽  
Author(s):  
M.I. Ivanov ◽  
G.M. Lukashenko
1970 ◽  
Vol 6 (6) ◽  
pp. 16-18
Author(s):  
SK Chakrabarti ◽  
IS Jha ◽  
BP Singh

The large asymmetry observed in the properties of mixing of indium-sodium liquid alloy is discussed on the basis of quasi-lattice chemical model. A special attention is given to the concentration dependence of free energy of mixing, entropy of mixing and heat of mixing. The results explain the observed asymmetry in the properties of mixing of InNa liquid alloys around equi-atomic composition. Key words: Complex forming alloys; Binary liquid alloys; Quasi-lattice model; Thermodynamic properties. DOI: 10.3126/sw.v6i6.2627 Scientific World, Vol. 6, No. 6, July 2008 16-18


2011 ◽  
Vol 519 (1-2) ◽  
pp. 1-5 ◽  
Author(s):  
O.E. Awe ◽  
Y.A. Odusote ◽  
L.A. Hussain ◽  
O. Akinlade

2006 ◽  
Vol 20 (23) ◽  
pp. 3319-3340
Author(s):  
O. E. AWE ◽  
O. AKINLADE ◽  
L. A. HUSSAIN

A Quasi-lattice model of liquid binary mixtures has been used to establish a model for calculating some thermodynamic properties of compound forming ternary liquid alloys. The effect of varying Z on the concentration fluctuations was also investigated. Results obtained for limiting case of the model are presented and compared with that obtained by Bhatia and Singh for binary liquid alloys. A framework for calculating the Warren Cowley short range order for ternary liquid alloys as a function of Z is also formulated.


2021 ◽  
Vol 5 (2) ◽  
pp. 1-6
Author(s):  
Abodunrin OW

The thermodynamic models based on cluster of two and four atoms were considered to obtain the thermodynamic properties of liquid binary alloys. The four liquid alloys are candidates of homo-coordination / self-coordination. The values of chemical short range order, Concentration fluctuation and excess stability functions and the differences in models computed for Cu-Pb, Li-Mg, Cd-Ga and Bi-Cd binary liquid alloys are presented.


1970 ◽  
Vol 26 ◽  
pp. 40-45
Author(s):  
S. K. Chakrabarti ◽  
B. K. Jha ◽  
I. S. Jha

Cadmium is a highly reactive metal. At the time of formation of binary alloys in liquidphase it often forms complexes. In the present work we have considered two such complexforming binary liquid alloys of cadmium e.g. Cd-Na and Cd-Mg. The former alloy showsanomaly in its thermodynamic properties of mixing. On the other hand, the alloyingbehavior of the latter one is symmetric around the equi-atomic composition. We havecomputed their entropy of mixing (SM) for different concentrations of the ingredients byusing the quasi-lattice chemical model. The results explain the observed anomaly as well assymmetry in SM of the present alloys.Keywords: Binary liquid alloys of cadmium; Quasi-lattice chemical model; Entropy of mixingDOI: 10.3126/jncs.v26i0.3629Journal of Nepal Chemical SocietyVol. 26, 2010Page:40-45


Sign in / Sign up

Export Citation Format

Share Document