Study of the rotational motion of the iminoxyl radical in different polymers

1969 ◽  
Vol 11 (2) ◽  
pp. 474-482 ◽  
Author(s):  
V.B. Stryukov ◽  
G.V. Korolev
Keyword(s):  
Rotational Motion ◽  
Iminoxyl Radical

Tyrosine-Selective Bioconjugation with Iminoxyl Radicals

2020 ◽  
Author(s):  
Katsuya Maruyama ◽  
Takashi Ishiyama ◽  
Yohei Seki ◽  
Kounosuke Oisaki ◽  
Motomu Kanai
Keyword(s):  
Reaction Time ◽  
Steric Hindrance ◽  
Room Temperature ◽  
Water Soluble ◽  
Light Irradiation ◽  
Sodium Ascorbate ◽  
Iminoxyl Radical ◽  
Short Reaction Time ◽  
Modified Peptides ◽  
The Stability

A novel Tyr-selective protein bioconjugation using the water-soluble persistent iminoxyl radical is described. The conjugation proceeded with high Tyr-selectivity and short reaction time under biocompatible conditions (room temperature in buffered media under air). The stability of the conjugates was tunable depending on the steric hindrance of iminoxyl. The presence of sodium ascorbate and/or light irradiation promoted traceless deconjugation, restoring the native Tyr structure. The method is applied to the synthesis of a protein-dye conjugate and further derivatization to azobenzene-modified peptides.

scholarly journals Are External Magnetic Disturbances Suppressed by Magnetometer Noise when Estimating a Nanosatellite’s Rotational Motion?

2020 ◽  
Vol 53 (2) ◽  
pp. 14888-14893
Author(s):  
Demet Cilden-Guler ◽  
Zerefsan Kaymaz ◽  
Chingiz Hajiyev
Keyword(s):  
Rotational Motion ◽  
Magnetic Disturbances
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