Mössbauer study of 170Yb in some metals and metal-like compounds' isomer shift measurements and intermediate valence states of ytterbium

1978 ◽  
Vol 26 (12) ◽  
pp. iv
Author(s):  
P. Bonville ◽  
P. Imbert ◽  
G. Jehanno ◽  
F. Gonzalez-Jimenez
2003 ◽  
Vol 792 ◽  
Author(s):  
M. Singh ◽  
Anjana Dogra ◽  
Ravi Kumar

ABSTRACTA series of samples of Mg0.9Mn0.1InxFe2-xO4 for x=0, 0.3, 0.5 were prepared by conventional solid-state technique. The spinel structure of this ferrite was confirmed by X-ray diffraction technique. The samples were irradiated with 50 MeV Li3+ ions with fluence 5×1013 ions/cm2. The Mössbauer studies were performed on unirradiated as well as on irradiated samples. Mössbauer study for unirradiated samples show insignificant variation of isomer shifts at both the tetrahedral and octahedral sites. On irradiation isomer shift changes from negative to positive values. This anomalous character of isomer shift after irradiation is due to a change in the electronic configuration of Fe3+ ions. The quadrupole splitting of unirradiated samples are negligibly small, indicates the presence of cubic symmetry at both the sites. On irradiation appreciable changes are observed in quadrupole splitting due to the presence of lattice strain. On irradiation super-exchange interaction energy is weakened which decrease the hyperfine field. PACS: 61.80, 76.80, 61.72


1990 ◽  
Vol 89 (1-2) ◽  
pp. 143-152 ◽  
Author(s):  
K. Tomala ◽  
D. Weschenfelder ◽  
G. Czjzek ◽  
E. Holland-Moritz

2000 ◽  
Vol 14 (15) ◽  
pp. 1593-1601 ◽  
Author(s):  
M. SINGH ◽  
B. S. CHAUHAN

The effect of In 3+ and Al 3+ substitution in Mg–Mn ferrite has been studied from Mössbauer analyzes of Mg 0.9 Mn 0.1 M x Fe 2-x O 4(0 ≤x≤0.9) and Mg 0.9 Mn 0.1 Fe 2-y O 4(0≤y≤0.5) ferrites. The internal magnetic field has been found to decrease at tetrahedral and octahedral sites when the concentration of In 3+ and Al 3+ ions is successively increased. A ferromagnetic relaxation followed by paramagnetic transition is observed for higher concentrations of In 3+ ions, it has been inferred that a larger concentration of In 3+ ions enhances relaxation effects. The observed values of isomer shift corresponding to Fe 3+ ions at A as well as B sites in both the series show an insignificant variation with increase in the concentration of In 3+ and Al 3+ ions. It is also inferred that all the samples show negligible value of quadrupole splitting with in experimental errors. The occupancy ratio increases with increase of In 3+ ions and the occupancy ratio decreases with increase of concentration of Al 3+ ions. The results of occupancy of Fe 3+ ions at B to A site, as obtained from Mössbauer studies are in conformity with the cation distribution used to explain variation of 4πMs and μ0.


1978 ◽  
Vol 17 (2) ◽  
pp. 758-764 ◽  
Author(s):  
J. W. Schweitzer

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