Construction of higher-order algebraic one-step schemes in stiff BVPs

1993 ◽  
Vol 13 (1-3) ◽  
pp. 199-208 ◽  
Author(s):  
B.A. Schmitt ◽  
Z. Mei
2012 ◽  
Vol 33 (4) ◽  
pp. 556-564 ◽  
Author(s):  
Farzad Bazdidi-Tehrani ◽  
Alireza Imanifar ◽  
Siavash Khajehhasani ◽  
Mehran Rajabi-Zargarabadi

2020 ◽  
Vol 3 (1) ◽  
Author(s):  
Qiupeng Peng ◽  
Shi-Jun Li ◽  
Bei Zhang ◽  
Donghui Guo ◽  
Yu Lan ◽  
...  

AbstractHigher-order cycloadditions are a powerful strategy for the construction of polycycles in one step. However, an efficient and concise version for the induction of asymmetry is lacking. N-heterocyclic carbenes are widely used organocatalysts for asymmetric synthesis and could be an ideal choice for enantioselective higher-order cycloadditions. Here, we report an enantioselective [10 + 2] annulation between catalytically formed aza-benzofulvene intermediates and trifluoromethyl ketone derivatives. This protocol exhibits a wide scope, high yields, and good ee values, reflecting a robust and efficient higher-order cycloaddition. Density functional theory calculations provide an accurate prediction of the reaction enantioselectivity, and in-depth insight to the origins of stereocontrol.


2002 ◽  
Vol 18 (5) ◽  
pp. 1040-1085 ◽  
Author(s):  
Donald W.K. Andrews

It is well known that a one-step scoring estimator that starts from any N1/2-consistent estimator has the same first-order asymptotic efficiency as the maximum likelihood estimator. This paper extends this result to k-step estimators and test statistics for k ≥ 1, higher order asymptotic efficiency, and general extremum estimators and test statistics.The paper shows that a k-step estimator has the same higher order asymptotic efficiency, to any given order, as the extremum estimator toward which it is stepping, provided (i) k is sufficiently large, (ii) some smoothness and moment conditions hold, and (iii) a condition on the initial estimator holds.For example, for the Newton–Raphson k-step estimator based on an initial estimator in a wide class, we obtain asymptotic equivalence to integer order s provided 2k ≥ s + 1. Thus, for k = 1, 2, and 3, one obtains asymptotic equivalence to first, third, and seventh orders, respectively. This means that the maximum differences between the probabilities that the (N1/2-normalized) k-step and extremum estimators lie in any convex set are o(1), o(N−3/2), and o(N−3), respectively.


1984 ◽  
Vol 25 (1) ◽  
pp. 93-96
Author(s):  
Lee A. Rubel

We confine ourselves, for simplicity, to first-order algebraic differential equations (ADE's), although analogous considerations may be made for higher-order ADE's:P(x, y(x), y'(x)) = 0. (*)A motion of (*) is a change of independent variable that takes solutions to solutions, that is, a suitable map <p of the underlying interval I into itself so that if y is a solution of (*) then y ° φ is a solution of (*), i.e.


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