Determination of vapor-liquid equilibria by total pressure measurements for four binary silicon compound systems: tetramethoxy silane + p-xylene, tetramethoxy silane + n-nonane, tetraethoxy silane +p-xylene, and tetraethoxy silane + n-nonane

1990 ◽  
Vol 58 (1-2) ◽  
pp. 181-189 ◽  
Author(s):  
Masahiro Kato ◽  
Hiroyuki Tanaka ◽  
Kazunori Aizawa
1999 ◽  
Vol 54 (11) ◽  
pp. 1410-1416 ◽  
Author(s):  
H. Oppermann ◽  
H. Dao Quoc ◽  
A. Morgenstern

The thermodynamical data of solid aluminium lanthanum chloride LaAlCl6 have been obtained by determination of the decomposition equilibria from total pressure measurements. The melting diagram was determined by DTA. The chemical transport of LaCl3 with AlCl3 is suggesting the existence of the gaseous complex LaAl3Cl12. The data are:ΔH(LaAlCl6f,298) =-427,1 ±2,5 kcal/mol, S°(LaAlCl6,f,298) = 61 ±2,5 cal/K-mol,Δ(LaAl3Cl12,g ,298) =-712 ± 7 kcal/mol, S°(LaAl3Cl12,g,298) = 205 ± 3 cal/K-mol.


1971 ◽  
Vol 14 (4) ◽  
pp. 252-256 ◽  
Author(s):  
Kunio Nagahama ◽  
Seijiro Suda ◽  
Toshikatsu Hakuta ◽  
Mitsuho Hirata

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