VARIABLES AFFECTING THE COUNTING OF C*SUP 14/ IN THE LIQUID PHASE WITH A GEIGER-MUELLER TUBE. PART 1. DETERMINATION OF VAPOR-LIQUID EQUILIBRIA OF A TERNARY MIXTURE WITH A RADIOACTIVE TRACER. PART 2 (thesis)

1953 ◽  
Author(s):  
T.T. Szabo
Keyword(s):  
Liquid Phase ◽  
Ternary Mixture ◽  
Radioactive Tracer ◽  
Vapor Liquid Equilibria ◽  
Vapor Liquid

scholarly journals Molecular Interactions at Vapor-Liquid Interfaces Binary Mixtures of Simple Fluids

2021 ◽  
Author(s):  
Simon Stephan ◽  
Hans Hasse
Keyword(s):  
Liquid Phase ◽  
Interfacial Properties ◽  
Binary Interaction ◽  
Binary Interaction Parameter ◽  
Gradient Theory ◽  
Solution Theory ◽  
Conformal Solution Theory ◽  
Vapor Liquid Equilibria ◽  
Dynamics Simulations ◽  
Vapor Liquid

Properties of vapor-liquid equilibria and planar interfaces of binary Lennard-Jones truncated and shifted mixtures were investigated with molecular dynamics simulations, density gradient theory, and conformal solution theory at constant liquid phase composition and temperature. The results elucidate the influence of the liquid phase interactions on the interfacial properties (surface tension, surface excess, interfacial thickness, and enrichment). The studied mixtures differ in the ratios of the dispersion energies of the two components ɛ2/ɛ1 and the binary interaction parameter ξ. By varying ξ and ɛ2/ɛ1, a variety of types of phase behavior is covered by this paper. The dependence of the interfacial properties on the variables ξ and ɛ2/ɛ1 reveals regularities that can be explained by conformal solution theory of the liquid phase. It is thereby shown that the interfacial properties of the mixtures are dominated by the mean liquid phase interactions whereas the vapor phase has only a minor influence.

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