PHASE CHANGES IN THE NIOBIUM–HYDROGEN SYSTEM—II. LOW TEMPERATURE HYDRIDE PHASE TRANSITIONS

Author(s):  
B.J. MAKENAS ◽  
H.K. BIRNBAUM
1983 ◽  
Vol 4 (1) ◽  
pp. 37-45 ◽  
Author(s):  
P. E. Tomaszewski ◽  
K. Łukaszewicz

1991 ◽  
Vol 175 (3-4) ◽  
pp. 301-309 ◽  
Author(s):  
C.H. Chen ◽  
S-W. Cheong ◽  
D.J. Werder ◽  
A.S. Cooper ◽  
L.W. Rupp

1998 ◽  
Vol 53 (1-2) ◽  
pp. 27-37 ◽  
Author(s):  
M. Windhaus ◽  
B. D. Mosel ◽  
W. Müller-Warmuth

Abstract 57 Fe Mössbauer spectra have been measured at various temperatures between 4.2 K and 300 K for iron langbeinites A 2 Fe 2^04)3 with A = K, NH 4 , Rb, T1 and magnesium, manganese and cadmium lang-beinites doped with Fe" + . The spectra revealed several contributions whose isomer shifts and quadru-pole splittings have been obtained by fitting program routines. For the high-temperature cubic phases two crystallographically non-equivalent iron sites have been identified, characteristic of Fe2+ in the high-spin state. Abrupt changes of the quadrupole couplings indicated phase transitions; in some cases, the spectra have also revealed several sites for Fe2+ in low temperature phases. From the temperature dependences, phase transition temperatures, crystal field splittings and Debye temperatures have been derived.


2003 ◽  
Vol 285 (1) ◽  
pp. 19-26 ◽  
Author(s):  
Yoshiaki Uesu ◽  
Ryuhei Nakai ◽  
Noritaka Kato ◽  
Carole Menoret ◽  
Jean-Michel Kiat ◽  
...  

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