Mössbauer Studies of Fe2+ in Iron Langbeinites and other Crystals with Langbeinite Structure

1998 ◽  
Vol 53 (1-2) ◽  
pp. 27-37 ◽  
Author(s):  
M. Windhaus ◽  
B. D. Mosel ◽  
W. Müller-Warmuth
Keyword(s):  
Phase Transition ◽  
Phase Transitions ◽  
High Temperature ◽  
Low Temperature ◽  
High Spin State ◽  
Cubic Phases ◽  
Debye Temperatures ◽  
Phase Transition Temperatures ◽  
Abrupt Changes ◽  
Temperature Dependences

Abstract 57 Fe Mössbauer spectra have been measured at various temperatures between 4.2 K and 300 K for iron langbeinites A 2 Fe 2^04)3 with A = K, NH 4 , Rb, T1 and magnesium, manganese and cadmium lang-beinites doped with Fe" + . The spectra revealed several contributions whose isomer shifts and quadru-pole splittings have been obtained by fitting program routines. For the high-temperature cubic phases two crystallographically non-equivalent iron sites have been identified, characteristic of Fe2+ in the high-spin state. Abrupt changes of the quadrupole couplings indicated phase transitions; in some cases, the spectra have also revealed several sites for Fe2+ in low temperature phases. From the temperature dependences, phase transition temperatures, crystal field splittings and Debye temperatures have been derived.

scholarly journals Phase Transition and Electrical Properties in Cs2SeO4.Te(OH)6

2011 ◽  
Vol 7 (3) ◽  
pp. 1448-1456
Author(s):  
Litaiem H. ◽  
Garcia-Granda S. ◽  
Dammak M. ◽  
Mhiri T.
Keyword(s):  
Phase Transition ◽  
Thermal Analysis ◽  
Phase Transitions ◽  
High Temperature ◽  
Paraelectric Phase ◽  
Complex Impedance ◽  
Paraelectric Phase Transition ◽  
Two Phase ◽  
Impedance Measurements ◽  
Temperature Dependences

Dielectric investigations in the temperature and frequency 300- 600 K and 0,1KHz–13MHz, respectively, show that cesium selenate tellurate Cs2SeO4.Te(OH)6 (CsSeTe) exhibits two phase transitions at 490 and 525 K. The a.c. complex impedance measurements performed on CsSeTe material show an important level of conductivity at high temperature, attributed to the motion of H+ proton. This behavior is in agreement with the presence of the super- protonic phase transition in CsSeTe compound at 525K. This assignment was confirmed by the analysis of the M"/M"max spectra. The temperature dependences of ε΄r and tanδ indicate that the anomaly at 490K is attributed to a ferroelectric-paraelectric phase transition. Thermal analysis at high temperature, DSC, DTA, TG,  Ms/z= 18 and Ms/z= 32 confirm the presence of the two transitions already cited, the temperature and the nature of the decomposition.  

scholarly journals The phase transitions of 4-aminopyridine-based indolocarbazoles: twinning, local- and pseudo-symmetry

2019 ◽  
Vol 75 (1) ◽  
pp. 97-106 ◽  
Author(s):  
Thomas Kader ◽  
Berthold Stöger ◽  
Johannes Fröhlich ◽  
Paul Kautny
Keyword(s):  
Phase Transition ◽  
Phase Transitions ◽  
High Temperature ◽  
Low Temperature ◽  
Group Symmetry ◽  
Temperature Phase ◽  
Space Group ◽  
Local Symmetries ◽  
Group Symmetries ◽  
Low Temperature Phase

The phase transitions and polymorphism of three 4-aminopyridine-based indolocarbazole analogues are analyzed with respect to symmetry relationships and twinning. Seven polymorphs were structurally characterized using single-crystal diffraction. 5NICz (the indolo[3,2,1-jk]carbazole derivative with the C atom in the 5-position replaced by N) crystallizes as a P21/a high-temperature (270 K) polymorph and as a Pca21 low-temperature (150 K) polymorph. Even though their space-group symmetry is not related by a group–subgroup relationship, the local symmetries of both belong to the same order–disorder (OD) groupoid family. Both are polytypes of a maximum degree of order and are twinned by point operations of the other polytype. 2NICz (C atom in the 2-position replaced by N) likewise crystallizes in a high-temperature (Pcca, 280 K) polymorph and a low-temperature (P21/c, 150 K) polymorph. Here, the space-group symmetries are related by a group–subgroup relationship. The low-temperature phase is twinned by the point operations lost on cooling. The crystal structure of bulk 2,5NICz (N-substitution at the 2- and 5-positions) was unrelated to 2NICz and 5NICz and no phase transition was observed. Isolated single crystals of a different polymorph of 2,5NICz, isotypic with 2NICz, were isolated. However, the analogous phase transition in this case takes place at distinctly higher temperatures (> 300 K).

scholarly journals Thermal, ferroelastic, and structural properties near phase transitions of organic–inorganic perovskite type [NH3(CH2)3NH3]CdBr4 crystals

RSC Advances ◽  
2021 ◽  
Vol 11 (29) ◽  
pp. 17622-17629
Author(s):  
Ae Ran Lim
Keyword(s):  
Phase Transition ◽  
Phase Transitions ◽  
Thermal Behavior ◽  
Structural Properties ◽  
Structural Dynamics ◽  
Transition Temperatures ◽  
Inorganic Perovskite ◽  
Phase Transition Temperatures ◽  
Perovskite Type

We studied the thermal behavior and structural dynamics of [NH3(CH2)3NH3]CdBr4 near phase transition temperatures.

INDUCED CHANGES OF THERMOTROPIC PROPERTIES OF PHASE TRANSITIONS BETWEEN SMECTIC A MESOPHASE AND ISOTROPIC LIQUID: EFFECT OF SURFACES

2006 ◽  
Vol 20 (14) ◽  
pp. 821-833 ◽  
Author(s):  
ARIF NESRULLAJEV ◽  
ŞENER OKTIK
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Phase Transition ◽  
Phase Transitions ◽  
Isotropic Liquid ◽  
Smectic A ◽  
Phase Transition Temperatures ◽  
Smectic A Phase ◽  
Induced Changes ◽  
Thermotropic Properties

In this work, the effect of thin films on the thermotropic and thermo-optical properties and peculiarities of the phase transitions between the smectic A and isotropic liquid have been investigated. Peculiarities of the heterophase regions of the straight smectic A-isotropic liquid and reverse isotropic liquid-smectic A phase transitions have been studied. Change of morphologic properties of the heterophase regions, shift of the phase transition temperatures and the change of temperature widths of these heterophase regions under thin film influence have been observed.

Structural-phase transition in (Cu2Te)2−x(ZnTe)x at high temperature

2021 ◽  
pp. 2150113
Author(s):  
H. B. Gasimov ◽  
R. M. Rzayev
Keyword(s):  
Phase Transition ◽  
Phase Transitions ◽  
High Temperature ◽  
Single Crystals ◽  
Structural Phase ◽  
X Ray Diffraction ◽  
X Ray ◽  
Temperature Range ◽  
Xrd Study ◽  
Xrd Method

Cu2Te single crystal was grown by the Bridgman method. X-ray diffraction (XRD) study of Cu2Te single crystals in the temperature range of 293–893 K was performed and possible phase transitions in the mentioned range of temperature have been investigated. (Cu2Te)[Formula: see text](ZnTe)[Formula: see text] single crystals also were grown with [Formula: see text], 0.05, 0.10 concentrations and structural properties of the obtained single crystals were investigated by the XRD method in the temperature range 293–893 K. Lattice parameters and possible phase transitions in the mention temperature range were determined for (Cu2Te)[Formula: see text](ZnTe)[Formula: see text] single crystals for [Formula: see text], 0.05, 0.10 concentrations.

Phase coexistence and the magnetic glass-like phase associated with the Morin type spin reorientation phase transition in SmCrO3

RSC Advances ◽  
2016 ◽  
Vol 6 (93) ◽  
pp. 90255-90262 ◽  
Author(s):  
Malvika Tripathi ◽  
R. J. Choudhary ◽  
D. M. Phase
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
Low Temperature ◽  
Phase Coexistence ◽  
Spin Reorientation ◽  
Reorientation Process ◽  
Magnetic Glass

SmCrO3 undergoes a discontinuous Morin type spin reorientation process due to discrete flipping of Cr3+ ions from the high temperature Γ4 to low temperature Γ1 configuration.

High- and low-temperature phases in isostructural 4-chloro-3-nitroaniline and 4-iodo-3-nitroaniline

2014 ◽  
Vol 70 (12) ◽  
pp. 1153-1160 ◽  
Author(s):  
Jan Fábry ◽  
Michal Dušek ◽  
Přemysl Vaněk ◽  
Iegor Rafalovskyi ◽  
Jiří Hlinka ◽  
...  
Keyword(s):  
Phase Transitions ◽  
High Temperature ◽  
Low Temperature ◽  
Hydrogen Bonds ◽  
Primary Amine ◽  
Zigzag Chain ◽  
Temperature Phase ◽  
Scanning Calorimetry ◽  
Acta Cryst ◽  
Graph Set

The structures of 4-chloro-3-nitroaniline, C6H5ClN2O2, (I), and 4-iodo-3-nitroaniline, C6H5IN2O2, (II), are isomorphs and both undergo continuous (second order) phase transitions at 237 and 200 K, respectively. The structures, as well as their phase transitions, have been studied by single-crystal X-ray diffraction, Raman spectroscopy and difference scanning calorimetry experiments. Both high-temperature phases (293 K) show disorder of the nitro substituents, which are inclined towards the benzene-ring planes at two different orientations. In the low-temperature phases (120 K), both inclination angles are well maintained, while the disorder is removed. Concomitantly, thebaxis doubles with respect to the room-temperature cell. Each of the low-temperature phases of (I) and (II) contains two pairs of independent molecules, where the molecules in each pair are related by noncrystallographic inversion centres. The molecules within each pair have the same absolute value of the inclination angle. The Flack parameter of the low-temperature phases is very close to 0.5, indicating inversion twinning. This can be envisaged as stacking faults in the low-temperature phases. It seems that competition between the primary amine–nitro N—H...O hydrogen bonds which form three-centred hydrogen bonds is the reason for the disorder of the nitro groups, as well as for the phase transition in both (I) and (II). The backbones of the structures are formed by N—H...N hydrogen bonding of moderate strength which results in the graph-set motifC(3). This graph-set motif forms a zigzag chain parallel to the monoclinicbaxis and is maintained in both the high- and the low-temperature structures. The primary amine groups are pyramidal, with similar geometric values in all four determinations. The high-temperature phase of (II) has been described previously [Gardenet al.(2004).Acta Cryst.C60, o328–o330].

35Cl NQR Studies of Hexachlorometallates(IV) with Organic Cations, A2 [MCl6] and A'[MCl6], M=Sn, Te, Pb and A+, A'2+ = Organic Cation

1990 ◽  
Vol 45 (3-4) ◽  
pp. 293-302 ◽  
Author(s):  
Dirk Borchers ◽  
Alarich Weiss
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
Low Temperature ◽  
Resonance Line ◽  
Organic Cation ◽  
Phase Changes ◽  
Organic Cations ◽  
Temperature Phase ◽  
35Cl Nqr ◽  
Low Temperature Phase

Abstract35Cl NQR spectra of eleven hexachlorometallates (IV) A1 [MCl6] and A'[MCl6], M = Sn, Te, Pb, and A+ =ethylammonium, 4-picolinium, anilinium, triethylammonium, chinoxalinium, and piperi-dinium ions, and A'2+ = 1.3-propylenediammonium ion, have been observed as a function of tem-perature. The ethylammonium hexachlorometallates(IV) (C2H5 NH3)2 [MCl6], M = Sn, Te, show a phase transition at 128.8 K and 204 K, respectively. Both compounds yield a single resonance line in their high temperature phases. In case of the stannate this single 35Cl resonance line splits up into two lines at Tc = 128.8 K, whereas for the tellurate no 35Cl NQR signals could be found in the low temperature phase. A phase transition was also found for the 1.3-propylenediammonium hexa-chlorostannate(IV) at 287 K where the six line NQR spectrum of the low temperature phase changes into a four line spectrum. In contrast, the corresponding plumbate shows no transition. All other compounds studied contain distorted [MCl6]2- octahedra, and therefore they yield more than one 35Cl resonance line. The complexes have been investigated in the temperature range temperature where the lines fade out. In case of the hexachlorostannates(IV) with the ethylammonium, the 1.3-propylenediammonium and the triethylammonium ions, the crystal structures of the compounds are known and compared with the results of the 35Cl NQR spectroscopy.

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