Mechanistic Perspectives on Stereocontrol in Lewis Acid-Mediated Radical Polymerization

2015 ◽  
pp. 189-258 ◽  
Author(s):  
Benjamin B. Noble ◽  
Michelle L. Coote
Keyword(s):  
Radical Polymerization ◽  
Lewis Acid

Efficient Lewis Acid-Catalyzed Stereocontrolled Radical Polymerization of Acrylamides

2001 ◽  
Vol 123 (29) ◽  
pp. 7180-7181 ◽  
Author(s):  
Yutaka Isobe ◽  
Daigo Fujioka ◽  
Shigeki Habaue ◽  
Yoshio Okamoto
Keyword(s):  
Radical Polymerization ◽  
Lewis Acid ◽  
Acid Catalyzed

The Bis(allyl)bismuth Cation: A Reagent for Direct Allyl Transfer by Lewis Acid Activation and Controlled Radical Polymerization

2012 ◽  
Vol 51 (52) ◽  
pp. 13011-13015 ◽  
Author(s):  
Crispin Lichtenberg ◽  
Fangfang Pan ◽  
Thomas P. Spaniol ◽  
Ulli Englert ◽  
Jun Okuda
Keyword(s):  
Radical Polymerization ◽  
Lewis Acid ◽  
Controlled Radical Polymerization ◽  
Acid Activation

Lewis acid-surfactant complex catalyzed polymerization in aqueous dispersed media: cationic or radical polymerization?

2020 ◽  
Vol 11 (36) ◽  
pp. 5757-5766
Author(s):  
Aurélie Destephen ◽  
Luis Lezama ◽  
Nicholas Ballard
Keyword(s):  
Radical Polymerization ◽  
Lewis Acid ◽  
Surfactant Complex ◽  
Dispersed Media ◽  
Aqueous Dispersed Media ◽  
Catalyzed Polymerization

Evidence is presented that shows Lewis acid-surfactant complex catalyzed polymerization proceeds via a radical, not a cationic, mechanism.

Yb(NTf2)3/HFIP induced high isotacticity in atom transfer radical polymerization of methyl methacrylate

2018 ◽  
Vol 9 (38) ◽  
pp. 4711-4715 ◽  
Author(s):  
Sebastian Schaubach ◽  
Xiao-Yan Wang ◽  
Jun-Fang Li ◽  
Xiu-Li Sun ◽  
Sunewang R. Wang ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Lewis Acid ◽  
Atom Transfer ◽  
Highly Efficient

Highly efficient Lewis acid Yb(NTf2)3 (1–8 mol%) for a high triad isotacticity (up to 69%) in bisoxazoline/copper mediated ATRP of MMA in HFIP is described.

scholarly journals Stereochemistry of Radical Polymerization of Vinyl Esters in the Presence of Lewis Acid

2000 ◽  
Vol 32 (8) ◽  
pp. 707-710 ◽  
Author(s):  
Kazunobu Yamada ◽  
Tamaki Nakano ◽  
Yoshio Okamoto
Keyword(s):  
Radical Polymerization ◽  
Lewis Acid ◽  
Vinyl Esters
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