Micro-mesoporous MCM-41/ZSM-5 supported Pt and Pd catalysts for hydroisomerization of C-8 aromatic fraction

2020 ◽  
Vol 603 ◽  
pp. 117764
Author(s):  
Aleksandr Glotov ◽  
Anna Vutolkina ◽  
Maria Artemova ◽  
Nataliya Demikhova ◽  
Ekaterina Smirnova ◽  
...  
2011 ◽  
Vol 76 (6) ◽  
pp. 923-932 ◽  
Author(s):  
Haihui Jiang ◽  
Ligang Gai ◽  
Yan Tian

Metal cation-doped MCM-41 (M-MCM-41, M=Al, Ce, Co, V, or Zr) supported Pd catalysts (Pd/M-MCM-41) were prepared by a solution-based reduction method. The catalysts were characterized by Xray diffraction (XRD) analysis, infrared spectroscopy (IR), scanning electron microscopy (SEM) and transmission electron microscopy (TEM), and further evaluated by selective hydrogenation of parachloronitrobenzene (p-CNB) in anhydrous ethanol. The metal cationcontaining Pd catalysts can efficiently enhance the selectivity for parachloroaniline (p-CAN). The highest selectivity of 96.5 % in the molar distribution for p-CNB to p-CAN was acquired over Pd (1.8 wt. %)/VMCM- 41 (Si/V=30, molar ratio) catalyst, and the corresponding turnover frequency (TOF) was 1.24?10-2 mol p-CNB mol-1 Pd s-1. Water molecules adsorbed by the support have important effects on both the catalytic activity of the sample and the selectivity for p-CAN. A water molecule-mediated catalytic hydrogenation is discussed.


2017 ◽  
Vol 75 (5) ◽  
pp. 479 ◽  
Author(s):  
Xiaodong Yang ◽  
Xinmiao Wang ◽  
Shanbin Gao ◽  
Anjie Wang
Keyword(s):  

2018 ◽  
Vol 44 (6) ◽  
pp. 3835-3847 ◽  
Author(s):  
Wonghil Chang ◽  
Hojun Kim ◽  
Jihyeon Oh ◽  
Byoung Joon Ahn
Keyword(s):  

2010 ◽  
Vol 383 (1-2) ◽  
pp. 211-216 ◽  
Author(s):  
A.M. Venezia ◽  
R. Murania ◽  
V. La Parola ◽  
B. Pawelec ◽  
J.L.G. Fierro

2019 ◽  
Vol 9 (3) ◽  
pp. 811-821 ◽  
Author(s):  
Zhao-Meng Wang ◽  
Li-Juan Liu ◽  
Bo Xiang ◽  
Yue Wang ◽  
Ya-Jing Lyu ◽  
...  

The catalytic activity decreases as –(SiO)3Mo(OH)(O) > –(SiO)2Mo(O)2 > –(O)4–MoO.


2000 ◽  
Vol 10 (PR7) ◽  
pp. Pr7-99-Pr7-102 ◽  
Author(s):  
G. Dosseh ◽  
D. Morineau ◽  
C. Alba-Simionesco
Keyword(s):  

2000 ◽  
Vol 10 (PR7) ◽  
pp. Pr7-95-Pr7-98 ◽  
Author(s):  
D. Morineau ◽  
F. Casas ◽  
C. Alba-Simionesco ◽  
A. Grosman ◽  
M.-C. Bellissent-Funel ◽  
...  

2013 ◽  
Vol 33 (10) ◽  
pp. 1696-1705
Author(s):  
Zhen LIU ◽  
Gang FENG ◽  
Chunyan PAN ◽  
Wang LI ◽  
Ping CHEN ◽  
...  
Keyword(s):  

2020 ◽  
Vol 12 (3) ◽  
pp. 03014-1-03014-5
Author(s):  
Fedir Ivashchyshyn ◽  
◽  
Dariusz Calus ◽  
Anna Pidluzhna ◽  
Piotr Chabecki ◽  
...  
Keyword(s):  

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