Oxodiperoxomolybdenum complex immobilized onto ionic liquid modified SBA-15 as an effective catalysis for sulfide oxidation to sulfoxides using hydrogen peroxide

2015 ◽  
Vol 255 ◽  
pp. 102-108 ◽  
Author(s):  
Carlos J. Carrasco ◽  
Francisco Montilla ◽  
Luis Bobadilla ◽  
Svetlana Ivanova ◽  
José Antonio Odriozola ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Ionic Liquid ◽  
Sulfide Oxidation

scholarly journals Efficient and selective hydrogen peroxide-mediated oxidation of sulfides in batch and segmented and continuous flow using a peroxometalate-based polymer immobilised ionic liquid phase catalyst

2015 ◽  
Vol 17 (3) ◽  
pp. 1559-1571 ◽  
Author(s):  
S. Doherty ◽  
J. G. Knight ◽  
M. A. Carroll ◽  
J. R. Ellison ◽  
S. J. Hobson ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Ionic Liquid ◽  
Liquid Phase ◽  
Continuous Flow ◽  
Sulfide Oxidation ◽  
Oxidation Of Sulfides ◽  
Highly Efficient ◽  
Mediated Oxidation

Highly efficient sulfide oxidation has been achieved under segmented and continuous flow using a peroxometalate-based polymer immobilised ionic liquid phase catalyst.

Hydrogen Peroxide Biosensor Based on Cellulose Diacetate Ionic Liquid Film Immobilizing Myoglobin

2012 ◽  
Vol 39 (9) ◽  
pp. 1358-1362
Author(s):  
She-Ying DONG ◽  
Guang-Zhe GU ◽  
Zhu-Qing YU ◽  
Yuan-Zhen ZHOU ◽  
Hong-Sheng TANG ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Ionic Liquid ◽  
Liquid Film ◽  
Cellulose Diacetate ◽  
Hydrogen Peroxide Biosensor

scholarly journals CARBOXYMETHYL CELLULOSE SYNTHESIS FROM TREATED OIL PALM EMPTY FRUIT BUNCH USING IONIC LIQUID AND HYDROGEN PEROXIDE

2021 ◽  
Vol 11 (4) ◽  
pp. 80-88
Author(s):  
Muzakkir Mohammad Zainol ◽  
Nurul Suhada Ab Rasid ◽  
Mohd Asmadi ◽  
Nor Aishah Saidina Amin
Keyword(s):  
Hydrogen Peroxide ◽  
Ionic Liquid ◽  
Carboxymethyl Cellulose ◽  
Proton Nuclear Magnetic Resonance ◽  
Sodium Chlorite ◽  
Cellulose Synthesis ◽  
Empty Fruit Bunch ◽  
Acid Pretreatment ◽  
Ionic Liquid Pretreatment ◽  
Magnetic Resonance Scanning

The synthesis of carboxymethyl cellulose (CMC) generally uses isolated crude cellulose with alkaline or acid pretreatment followed by bleaching with sodium chlorite. In this study, the simple [BMIM][Cl] ionic liquid was used as a solvent in the pretreatment process before conduct the bleaching process with hydrogen peroxide (H2O2) to isolate cellulose from empty fruit bunch (EFB) for further synthesis of CMC. The isolated crude EFB cellulose obtained was converted to CMC by adding 30 wt.% NaOH and various concentrations of sodium monochloroacetic acid (SMCA) at 55 °C for 3 h. The effects of SMCA concentration on the degree of substitution (DS) and CMC yield were investigated. The physicochemical properties of the CMC products were characterized using proton nuclear magnetic resonance, scanning electron microscope-energy dispersive spectrometry, X-ray diffraction, and thermogravimetric analysis. Based on the results, CMC was demonstrated to be synthesized using ionic liquid pretreatment with H2O2 bleaching. Carboxymethyl cellulose synthesized in this study showed a high DS of 0.82. The CMC synthesized from EFB cellulose through ionic liquid pretreatment presented good chemical and physical properties as that reported in other studies.

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