Recent developments in enzyme promiscuity for carbon–carbon bond-forming reactions

2015 ◽  
Vol 25 ◽  
pp. 115-123 ◽  
Author(s):  
Yufeng Miao ◽  
Mehran Rahimi ◽  
Edzard M Geertsema ◽  
Gerrit J Poelarends
Keyword(s):  
Enzyme Promiscuity ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions ◽  
Recent Developments

scholarly journals Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspective

2017 ◽  
Vol 13 ◽  
pp. 2214-2234 ◽  
Author(s):  
Yaroslav Dmitrievich Boyko ◽  
Valentin Sergeevich Dorokhov ◽  
Alexey Yu Sukhorukov ◽  
Sema Leibovich Ioffe
Keyword(s):  
Total Synthesis ◽  
Organic Synthesis ◽  
Michael Addition ◽  
High Reactivity ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions ◽  
Recent Developments ◽  
Michael Acceptors

Despite of their chemical instability and high reactivity, conjugated nitrosoalkenes are useful intermediates in target-oriented organic synthesis. The present review deals with carbon–carbon bond forming reactions involving Michael addition to α-nitrosoalkenes with a particular focus on recent developments in this methodology and its use in total synthesis.

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