Polynuclear transition metal complexes of metal⋯metal-bridging compartmental pyrazolate ligands

2009 ◽  
Vol 253 (21-22) ◽  
pp. 2698-2741 ◽  
Author(s):  
Julia Klingele ◽  
Sebastian Dechert ◽  
Franc Meyer
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Metal Metal

Planare Dicarbonylrhodium(I)- und -iridium(I) -Komplexe mit polarisierbaren aromatischen Liganden / Planar Dicarbonylrhodium(I) and Iridium(I) Complexes with Polarizable Aromatic Ligands

1973 ◽  
Vol 28 (3-4) ◽  
pp. 164-167 ◽  
Author(s):  
Rolf Aderjan ◽  
Hermann Breer ◽  
Heimo J. Keller ◽  
Herbert H. Rupp
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
General Type ◽  
Analytical Data ◽  
Metal Interactions ◽  
Metal Metal ◽  
Pmr Spectra

Some new transition metal complexes of the general type M(CO)2(L-L), where M stands for Ir(I), Rh(I) and L-L for a bidentate mononegative ligand are described. They were characterized by means of analytical data and their IR and PMR spectra. The chemical and solid state properties of these compounds are related to the strength of the intermolecular metal-metal interactions.

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