Heterocycle-fused cyclopentadienyl metal complexes: Heterocene synthesis, structure and catalytic applications

2021 ◽  
Vol 426 ◽  
pp. 213515 ◽  
Author(s):  
Ilya E. Nifant'ev ◽  
Pavel V. Ivchenko ◽  
Alexey A. Vinogradov
Keyword(s):  
Metal Complexes ◽  
Catalytic Applications ◽  
Cyclopentadienyl Metal

Catalytic Applications of Terpyridines and their Transition Metal Complexes

ChemCatChem ◽  
2011 ◽  
Vol 3 (9) ◽  
pp. 1384-1406 ◽  
Author(s):  
Andreas Winter ◽  
George R. Newkome ◽  
Ulrich S. Schubert
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Catalytic Applications

AlPO4 Molecular Sieves Modified with Metal Chelate Complexes

1992 ◽  
Vol 57 (4) ◽  
pp. 774-780 ◽  
Author(s):  
Stanisłav Kowalak ◽  
Kenneth J. Balkus
Keyword(s):  
Ion Exchange ◽  
Metal Complexes ◽  
Molecular Sieves ◽  
Metal Chelate ◽  
New Method ◽  
Cyclohexene Oxidation ◽  
Chelate Complexes ◽  
Pore System ◽  
Catalytic Applications ◽  
Exchange Properties

A new method for modification AlPO4 molecular sieves has been presented. Lack of ion-exchange properties makes the modification of aluminium phosphates for catalytic applications difficult. We have developed a method that involves the crystallization of AlPO4 molecular sieves around metal complexes. This results in encapsulation of the complexes within the intracrystalline pore system. Several metallophthalocyanines have been successfully encapsulated into AlPO4-5 and subsequently tested as catalysts for cyclohexene oxidation. Significant differences in activity result from the presence of different metallophthalocyanines.

DNA Cleavage by the Photolysis of Cyclopentadienyl Metal Complexes:  Mechanistic Studies and Sequence Selectivity of Strand Scission by CpW(CO)3CH3

2005 ◽  
Vol 70 (23) ◽  
pp. 9093-9102 ◽  
Author(s):  
Debra L. Mohler ◽  
Jennifer R. Downs ◽  
Allison L. Hurley-Predecki ◽  
Jennifer R. Sallman ◽  
Peter M. Gannett ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Dna Cleavage ◽  
Mechanistic Studies ◽  
Strand Scission ◽  
Sequence Selectivity ◽  
Cyclopentadienyl Metal

Photoinduced DNA Cleavage by Cyclopentadienyl Metal Complexes Conjugated to DNA Recognition Elements

2001 ◽  
Vol 3 (17) ◽  
pp. 2761-2764 ◽  
Author(s):  
Allison L. Hurley ◽  
Mitchell P. Maddox ◽  
Tricia L. Scott ◽  
Mark R. Flood ◽  
Debra L. Mohler
Keyword(s):  
Metal Complexes ◽  
Dna Cleavage ◽  
Dna Recognition ◽  
Recognition Elements ◽  
Cyclopentadienyl Metal
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