Effective growth and characterization of piperazinium orthophthalate single crystal yielding high second harmonic generation efficiency

Potassium iodide doped L-threonine (LTPI) single crystal with improved second harmonic generation efficiency, thermal stability and optical transmission was grown by low temperature solution growth method from aqueous solution. The grown crystal has 1.22 times second harmonic generation efficiency compared to the standard potassium dihydrogen phosphate. LTPI has a high optical transparency over a wide spectral range 245–1083 nm and lower cut-off at around 219 nm. LTPI crystallizes in the orthorhombic crystal structure with space group P212121. It is thermally stable up to 238°C. In this paper, the photoluminescence study, FT-IR spectroscopic study and elemental analysis have been presented.

Download Full-text

Synthesis, structural, thermal, mechanical, second harmonic generation efficiency and laser damage threshold studies of 4-dimethylaminopyridinium-3,5-dicarboxybenzoate trihydrate single crystal

Optical Materials ◽

10.1016/j.optmat.2017.06.011 ◽

2017 ◽

Vol 72 ◽

pp. 247-256 ◽

Cited By ~ 25

Author(s):

M. Rajkumar ◽

M. Saravanabhavan ◽

A. Chandramohan

Keyword(s):

Second Harmonic Generation ◽

Single Crystal ◽

Harmonic Generation ◽

Second Harmonic ◽

Damage Threshold ◽

Laser Damage Threshold ◽

Laser Damage ◽

Generation Efficiency ◽

Second Harmonic Generation Efficiency

Download Full-text

Enhancement of second harmonic generation efficiency: Growth and characterization of magnesium(II)-doped tetrakis(thiourea)nickel(II) chloride crystals

Optik ◽

10.1016/j.ijleo.2013.06.070 ◽

2014 ◽

Vol 125 (1) ◽

pp. 50-54 ◽

Cited By ~ 2

Author(s):

K. Muthu ◽

C.K. Mahadevan ◽

SP. Meenakshisundaram

Keyword(s):

Second Harmonic Generation ◽

Harmonic Generation ◽

Second Harmonic ◽

Generation Efficiency ◽

Second Harmonic Generation Efficiency

Download Full-text

Synthesis, Crystal Growth and Characterization of Organic Nonlinear Optical Co-Crystal: 4-N, N-dimethylamino-4-N-methyl-stilbazolium (3-nitrobenzenesulfonate)0.6I0.4

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.760-762.811 ◽

2013 ◽

Vol 760-762 ◽

pp. 811-815

Author(s):

Zhou Yang ◽

Yi Qiang Dai ◽

Hong Lei Hao ◽

Mojca Jazbinsek ◽

Peter Günter

Keyword(s):

Crystal Structure ◽

Crystal Growth ◽

Second Harmonic Generation ◽

Harmonic Generation ◽

Nonlinear Optical ◽

Second Harmonic ◽

Generation Efficiency ◽

Second Harmonic Generation Efficiency ◽

X Ray

This report presents the synthesis, growth, crystal structure determination and second-harmonic generation efficiency of nonlinear optical co-crystal 4-N, N-dimethylamino-4-N-methyl-stilbazolium (m-nitrobenzenesulfonate)0.6I0.4 (DSIMNS). It is co-crystal of two DAST (4-N,N-dimethylamino-4-N-methyl-stilbazolium tosylate) derivatives. X-ray crystallographic analyses revealed that the crystal structure of DSIMNS is monoclinic, with space group P21. Kurtz powder test has shown that DSIMNS exhibits a large second-harmonic generation efficiency 500 times of that of urea.

Download Full-text