Synthetic Applications of Polar Organometallic and Alkali-Metal Reagents Under Air and Moisture

2021 ◽  
pp. 100487
Author(s):  
Filippo Maria Perna ◽  
Paola Vitale ◽  
Vito Capriati
Keyword(s):  
Alkali Metal ◽  
Metal Reagents

Oxidative oxygen-nucleophilic bromo-cyclization of alkenyl carbonyl compounds without organic wastes using alkali metal reagents in green solvent

RSC Advances ◽  
2015 ◽  
Vol 5 (104) ◽  
pp. 85872-85878 ◽  
Author(s):  
Katsuhiko Moriyama ◽  
Chihiro Nishinohara ◽  
Toru Sugiue ◽  
Hideo Togo
Keyword(s):  
Alkali Metal ◽  
Carboxylic Acids ◽  
Carbonyl Compounds ◽  
Organic Wastes ◽  
Green Solvent ◽  
Cyclization Reactions ◽  
Metal Reagents

A bromo-lactonization of alkenyl carboxylic acids and a bromo-cyclization ofN-allyl amides as oxygen-nucleophilic bromo-cyclization reactions were developedviathe oxidative umpolung of bromide using alkali metal bromide and inorganic oxidant.

A Stable Methyl Phosphane Oxide/Lithium Amide Complex: a Structural and MO Calculational Investigation of the Mechanism of Proton Abstraction by Alkali Metal Reagents

1996 ◽  
Vol 35 (17) ◽  
pp. 1942-1944 ◽  
Author(s):  
Matthew G. Davidson ◽  
Robert P. Davies ◽  
Helen J. Mitchell ◽  
Rachel M. Oakley ◽  
Paul R. Raithby ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Lithium Amide ◽  
Proton Abstraction ◽  
Metal Reagents
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