Trioctylphosphonium room temperature ionic liquids with perfluorinated groups – Physical properties and surface behavior in comparison with the nonfluorinated analogues

Author(s):  
Daniel Rauber ◽  
Florian Heib ◽  
Michael Schmitt ◽  
Rolf Hempelmann
2011 ◽  
Vol 83 (17) ◽  
pp. 6717-6721 ◽  
Author(s):  
F. Fouzia Ouali ◽  
Nicola Doy ◽  
Glen McHale ◽  
Christopher Hardacre ◽  
Rile Ge ◽  
...  

2000 ◽  
Vol 72 (12) ◽  
pp. 2275-2287 ◽  
Author(s):  
Kenneth R. Seddon ◽  
Annegret Stark ◽  
María-José Torres

We report here the first systematic study of the effect of impurities and additives (e.g., water, chloride, and cosolvents) on the physical properties of room-temperature ionic liquids. Remarkably, it was discovered that the viscosity of mixtures was dependent mainly on the mole fraction of added molecular solvents and only to a lesser extent upon their identity, allowing viscosity changes during the course of a reaction to be entirely predictable. While the addition of such molecular solvents decreases the viscosity and density, chloride impurities, arising from the preparation of the ionic liquids, increase viscosity dramatically. The commonly used methods of preparation were validated with respect to chloride impurity.


2010 ◽  
Vol 152 (1-3) ◽  
pp. 9-13 ◽  
Author(s):  
Shiro Seki ◽  
Takeshi Kobayashi ◽  
Yo Kobayashi ◽  
Katsuhito Takei ◽  
Hajime Miyashiro ◽  
...  

2010 ◽  
Vol 493 (4-6) ◽  
pp. 259-262 ◽  
Author(s):  
Olga Russina ◽  
Lorenzo Gontrani ◽  
Barbara Fazio ◽  
Domenico Lombardo ◽  
Alessandro Triolo ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document