Synthesis and optical nonlinear property of NLO chromophores with alkoxy chains of different lengths using 8-hydroxy-1,1,7,7-tetramethyl-formyljulolidine as donor

2015 ◽  
Vol 112 ◽  
pp. 42-49 ◽  
Author(s):  
Haoran Wang ◽  
Fenggang Liu ◽  
Yuhui Yang ◽  
Huajun Xu ◽  
Chengcheng Peng ◽  
...  
RSC Advances ◽  
2014 ◽  
Vol 4 (63) ◽  
pp. 33312-33318 ◽  
Author(s):  
Maolin Zhang ◽  
Guowei Deng ◽  
Airui Zhang ◽  
Huajun Xu ◽  
Heyan Huang ◽  
...  

We have designed and synthesized a new chromophore having a 1,1,7,7-tetramethyljulolidine fused furan ring as the electron donor group to systematically investigate the role of the benzo[b]furan ring in NLO chromophores.


1995 ◽  
Vol 392 ◽  
Author(s):  
Xiaoguang Yang ◽  
Duncan McBranch ◽  
Basil Swanson ◽  
Dequan Li

AbstractThe design and synthesis of a family of calix[4]arene-based nonlinear optical (NLO) chromophores are discussed. The calixarene chromophores are macrocyclic compounds consisting of four simple D-π-A units bridged by methylene groups. These molecules were synthesized such that four D-π-A units of the calix[4]arene were aligned along the same direction with the calixarene in a cone conformation. These nonlinear optical super-chromophores were subsequently fabricated into covalently bound self-assembled monolayers on the surfaces of fused silica and silicon. Spectroscopic second harmonic generation (SHG) measurements were carried out to determine the absolute value of the dominant element of the second-order nonlinear susceptibility, d33, and the average molecular alignment, ψ. We find a value of d33 = 60 pm/V at a fundamental wavelength of 890 nm, and ψ˜ 36° with respect to the surface normal.


1972 ◽  
Vol 28 (5) ◽  
pp. 527-528 ◽  
Author(s):  
Th. Kenner ◽  
K. Ono ◽  
J. Rubenstein

Tetrahedron ◽  
2012 ◽  
Vol 68 (39) ◽  
pp. 8147-8155 ◽  
Author(s):  
M. Cidália R. Castro ◽  
M. Belsley ◽  
A. Maurício C. Fonseca ◽  
M. Manuela M. Raposo

2017 ◽  
Vol 2017 ◽  
pp. 1-11
Author(s):  
Yu-Hua Zhang ◽  
Xin-Xin Li ◽  
Xiang-Hong Wang ◽  
Zhen-Feng Huang ◽  
Han-Ling Mao ◽  
...  

Residual stress has significant influence on the performance of mechanical components, and the nondestructive estimation of residual stress is always a difficult problem. This study applies the relative nonlinear coefficient of critical refraction longitudinal (LCR) wave to nondestructively characterize the stress state of materials; the feasibility of residual stress estimation using the nonlinear property of LCR wave is verified. The nonlinear ultrasonic measurements based on LCR wave are conducted on components with known stress state to calculate the relative nonlinear coefficient. Experimental results indicate that the relative nonlinear coefficient monotonically increases with prestress and the increment of relative nonlinear coefficient is about 80%, while the wave velocity only decreases about 0.2%. The sensitivity of the relative nonlinear coefficient for stress is much higher than wave velocity. Furthermore, the dependence between the relative nonlinear coefficient and deformation state of components is found. The stress detection resolution based on the nonlinear property of LCR wave is 10 MPa, which has higher resolution than wave velocity. These results demonstrate that the nonlinear property of LCR wave is more suitable for stress characterization than wave velocity, and this quantitative information could be used for residual stress estimation.


2018 ◽  
Vol 157 ◽  
pp. 230-237 ◽  
Author(s):  
Huajun Xu ◽  
Nan Wang ◽  
Xiaoling Zhang ◽  
Zhonghui Li ◽  
Guowei Deng

2004 ◽  
Vol 846 ◽  
Author(s):  
Jessica Sinness ◽  
Olivier Clot ◽  
Scott R. Hammond ◽  
Nishant Bhatambrekar ◽  
Harrison L. Rommel ◽  
...  

ABSTRACTPrevious research in organic electro-optics has shown dramatic increases in the hyperpolarizablity of NLO chromophores. However, this large microscopic activity has not been translated to the macroscopic domain. The polymeric electro-optic (E-O) materials continue to lack the high noncentrosymmetric order of the poled chromophores within the matrix necessary for high E-O response (r33). This deficiency of order represents one major obstacle that must be overcome before E-O device commercialization can be achieved. This lack of order is partially due to the large dipole moments of high μβ chromophores, which cause the chromophores to align in a centrosymmetric fashion through intermolecular electrostatic interactions. However, quantum calculations show that when the aspect ratio between the width and length of the chromophore system is adjusted to be greater than 1.4:1 by adding bulky side groups around the center of the chromophore, it would prevent side on pairing of the chromophores. This would cause a decrease in the large areas of centrosymmetric aggregation and thus allow for easier poling of the system. Here we report the synthesis of a nanoscale NLO architecture in which dendritic moieties have been incorporated around the center of the chromophore to give a three dimensional structure in order to achieve the 1.4:1 aspect ratio and maximize the macroscopic order of the system.


1995 ◽  
Vol 413 ◽  
Author(s):  
D. W. Cheong ◽  
J. -I Chen ◽  
J. Kumar ◽  
S. K. Tripathy

ABSTRACTNonlinear optical (NLO) LB films of polyamic acid containing a stable NLO dye were prepared and imidized either chemically or thermally. The optical properties and molecular orientation of these LB films were studied. From the absorption spectra, we infer that the derivative of the pnitroazobenzene chromophore covalently attatched to polyamic acid did not show significant aggregation. Quadratic dependence of SHG on the number of layers in polyamic acid films indicated the noncentrosymmetric organization of polar NLO chromophores. A second-order nonlinear coefficient (d33) of 23.4 pm/V was observed at 1064 nm after absorption correction. In polyimide films, SH intensity was dramatically reduced due to the collapse of the layered structure upon imidization process. In-plane isotropy of the LB films of polyamic acid and polyimide were lost upon irradiation of polarized light.


2018 ◽  
Vol 42 (18) ◽  
pp. 15052-15060 ◽  
Author(s):  
Emine Çatal ◽  
Ergin Keleş ◽  
Nurgül Seferoğlu ◽  
Sylvain Achelle ◽  
Alberto Barsella ◽  
...  

A series of NLO chromophores based on a mono-, di- or tri-substituted triphenylamine core and allylidenemalononitrile fragments has been designed.


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