Electrochemical behavior of an anion-exchanger modified electrode prepared by sol–gel processing of an organofunctional silicon alkoxide

2004 ◽  
Vol 49 (4) ◽  
pp. 573-580 ◽  
Author(s):  
Cheng-Li Lin ◽  
Pei Tien ◽  
Lai-Kwan Chau

2001 ◽  
Vol 13 (3) ◽  
pp. 1124-1130 ◽  
Author(s):  
Pei Tien ◽  
Lai-Kwan Chau ◽  
Yu-Yun Shieh ◽  
Wen-Cheng Lin ◽  
Guor-Tzo Wei




2007 ◽  
Vol 79 (10) ◽  
pp. 3757-3763 ◽  
Author(s):  
Cheng-Li Lin ◽  
Cheng-Ling Shih ◽  
Lai-Kwan Chau


2013 ◽  
Vol 41 (8) ◽  
pp. 1249-1253 ◽  
Author(s):  
Jing RU ◽  
Jie DU ◽  
Hong-Xia HE ◽  
Xiao-Quan LU


2001 ◽  
Vol 55 (10) ◽  
pp. 1320-1326 ◽  
Author(s):  
Ta-Chuan Yeh ◽  
Pei Tien ◽  
Lai-Kwan Chau

A fiber-optic evanescent-wave absorption sensor was constructed on the basis of an organofunctionalized silica cladding. The cladding material was prepared by the sol-gel processing of an organofunctional silicon alkoxide, which contains a propyl-ethylenediamine triacetate (PEDTA) group. The PEDTA group can chelate with a Cu(II) ion to form a colored complex. Because of the large formation constant of the complexation reaction, a kinetic approach was used to quantify the Cu(II) content in samples. The sensor has a dynamic range of 0.5–100 ppm and a detection limit of 56 ppb. The measurement of the Cu(II) content in a scattering medium has also been demonstrated.



1988 ◽  
Vol 64 (5) ◽  
pp. 2717-2724 ◽  
Author(s):  
Guanghua Yi ◽  
Zheng Wu ◽  
Michael Sayer




2002 ◽  
Vol 126 (2) ◽  
pp. 161-165 ◽  
Author(s):  
Junying Zhang ◽  
Zhongtai Zhang ◽  
Zilong Tang ◽  
Zishan Zheng ◽  
Yuanhua Lin


2002 ◽  
Vol 740 ◽  
Author(s):  
Samuel T. Lutta ◽  
Hong Dong ◽  
Peter Y. Zavalij ◽  
M. Stanley Whittingham

ABSTRACTWe are exploring the synthesis and properties of structured vanadium oxides mainly nanotubes and nanorods. Nanotubes initially formed with surfactant templates have been readily exchanged with simple cations without change of the basal-plane structure. These compounds contain d-like vanadium oxide layers with the vanadium in VO6 octahedra. This structure is particularly suitable for redox reactions. In this paper we report on synthesis of vanadium oxide, (NH4)xV2O5-d·nH2O rods using organic polymer as template. This compound has been synthesized by sol-gel reaction and subsequent hydrothermal treatment. TGA, SEM, XRD and FTIR were used to characterize this compound. Thermal analysis of this compound shows that the fibrous morphology is maintained when it is heated in nitrogen and oxygen above 300 °C. However, in both cases the size of the fibers decreases. Performance of this compound as cathode material in secondary electrolyte has been investigated using LiPF6 as electrolyte. A capacity of 140 mAh/g was obtained which remained fairly constant with up to at least 10 cycles. We also investigated electrochemical behavior of thermal products.



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