Effects of the post-perovskite phase transition properties on the stability and structure of primordial reservoirs in the lower mantle of the Earth

2015 ◽  
Vol 432 ◽  
pp. 1-12 ◽  
Author(s):  
Yang Li ◽  
Frédéric Deschamps ◽  
Paul J. Tackley
2007 ◽  
Vol 104 (34) ◽  
pp. 13588-13590 ◽  
Author(s):  
D. L. Lakshtanov ◽  
S. V. Sinogeikin ◽  
K. D. Litasov ◽  
V. B. Prakapenka ◽  
H. Hellwig ◽  
...  

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1282
Author(s):  
Ioannis Deretzis ◽  
Corrado Bongiorno ◽  
Giovanni Mannino ◽  
Emanuele Smecca ◽  
Salvatore Sanzaro ◽  
...  

The realization of stable inorganic perovskites is crucial to enable low-cost solution-processed photovoltaics. However, the main candidate material, CsPbI3, suffers from a spontaneous phase transition at room temperature towards a photo-inactive orthorhombic δ-phase (yellow phase). Here we used theoretical and experimental methods to study the structural and electronic features that determine the stability of the CsPbI3 perovskite. We argued that the two physical characteristics that favor the black perovskite phase at low temperatures are the strong spatial confinement in nanocrystalline structures and the level of electron doping in the material. Within this context, we discussed practical procedures for the realization of long-lasting inorganic lead halide perovskites.


1999 ◽  
Vol 117 (5) ◽  
pp. 2561-2562 ◽  
Author(s):  
F. Namouni ◽  
C. D. Murray

2001 ◽  
Vol 28 (23) ◽  
pp. 4351-4354 ◽  
Author(s):  
Kei Hirose ◽  
Tetsuya Komabayashi ◽  
Motohiko Murakami ◽  
Ken-ichi Funakoshi

Author(s):  
Timon Hummel ◽  
Claude Coatantiec ◽  
Xavier Gnata ◽  
Tobias Lamour ◽  
Rémi Rivière ◽  
...  

AbstractThe measurement accuracy of recent and future space-based imaging spectrometers with a high spectral and spatial resolution suffer from the inhomogeneity of the radiances of the observed Earth scene. The Instrument Spectral Response Function (ISRF) is distorted due to the inhomogeneous illumination from scene heterogeneity. This gives rise to a pseudo-random error on the measured spectra. In order to assess the spectral stability of the spectrograph, stringent requirements are typically defined on the ISRF such as shape knowledge and the stability of the centroid position of the spectral sample. The high level of spectral accuracy is particularly crucial for missions quantifying small variations in the total column of well-mixed trace gases like $$\hbox {CO}_{2}$$ CO 2 . In the framework of the $$\hbox {CO}_{2}$$ CO 2 Monitoring Mission (CO2M) industrial feasibility study (Phase A/B1 study), we investigated a new slit design called 2D-Slit Homogenizer (2DSH). This new concept aims to reduce the Earth scene contrast entering the instrument. The 2DSH is based on optical fibre waveguides assembled in a bundle, which scramble the light in across-track (ACT) and along-track (ALT) direction. A single fibre core dimension in ALT defines the spectral extent of the slit and the dimension in ACT represents the spatial sample of the instrument. The full swath is given by the total size of the adjoined fibres in ACT direction. In this work, we provide experimental measurement data on the stability of representative rectangular core shaped fibre as well as a preliminary pre-development of a 2DSH fibre bundle. In our study, the slit concept has demonstrated significant performance gains in the stability of the ISRF for several extreme high-contrast Earth scenes, achieving a shape stability of $$<0.5{\%}$$ < 0.5 % and a centroid stability of $$<0.25 \ \text {pm}$$ < 0.25 pm (NIR). Given this unprecedented ISRF stabilization, we conclude that the 2DSH concept efficiently desensitizes the instrument for radiometric and spectral errors with respect to the heterogeneity of the Earth scene radiance.


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