A neutral Ni(II) acetylide-mediated radical polymerization of methyl methacrylate using the atom transfer radical polymerization method

2004 ◽  
Vol 40 (1) ◽  
pp. 97-102 ◽  
Author(s):  
Qing Shao ◽  
Hongmei Sun ◽  
Xingan Pang ◽  
Qi Shen
2003 ◽  
Vol 36 (8) ◽  
pp. 2591-2593 ◽  
Author(s):  
Vernon C. Gibson ◽  
Rachel K. O'Reilly ◽  
Duncan F. Wass ◽  
Andrew J. P. White ◽  
David J. Williams

1997 ◽  
Vol 30 (7) ◽  
pp. 2190-2193 ◽  
Author(s):  
David M. Haddleton ◽  
Christina B. Jasieczek ◽  
Michael J. Hannon ◽  
Andrew J. Shooter

2018 ◽  
Vol 18 (3) ◽  
pp. 537 ◽  
Author(s):  
Melahat Göktaş ◽  
Guodong Deng

Poly(methyl methacrylate)-b-poly(N-isopropylacrylamide) [PMMA-b-PNIPAM] block copolymers were obtained by a combination of redox polymerization and atom transfer radical polymerization (ATRP) methods in two steps. For this purpose, PMMA macroinitator (ATRP-macroinitiator) was synthesized by redox polymerization of methyl methacrylate and 3-bromo-1-propanol using Ce(NH4)2(NO3)6 as a catalyst. The synthesis of PMMA-b-PNIPAM block copolymers was carried out by means of ATRP of ATRP-macroinitiator and NIPAM at 60 °C. The block copolymers were obtained in high yield and high molecular weight. The characterization of products was accomplished by using multi instruments and methods such as nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, gel permeation chromatography, and thermogravimetric analysis.


2011 ◽  
Vol 124 (3) ◽  
pp. 2278-2286 ◽  
Author(s):  
Khezrollah Khezri ◽  
Vahid Haddadi-Asl ◽  
Hossein Roghani-Mamaqani ◽  
Mehdi Salami-Kalajahi

Polymer ◽  
2003 ◽  
Vol 44 (25) ◽  
pp. 7661-7669 ◽  
Author(s):  
Katsuhiro Yamamoto ◽  
Hiroyuki Tanaka ◽  
Masato Sakaguchi ◽  
Shigetaka Shimada

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