scholarly journals Trifluoromethyl functionalized sulfonated polytriazoles from diphenylphosphine oxide-based dialkyne via click polymerization: Effect of high content of phosphorus on the proton exchange membrane properties

2021 ◽  
pp. 110869
Author(s):  
Arijit Ghorai ◽  
Riddhi Kamble ◽  
Susanta Banerjee
RSC Advances ◽  
2016 ◽  
Vol 6 (16) ◽  
pp. 13478-13489 ◽  
Author(s):  
Asheesh Singh ◽  
Susanta Banerjee ◽  
Hartmut Komber ◽  
Brigitte Voit

A series of polytriazole copolymers were synthesized by the click polymerization of fluorinated dialkyne with a mixture of two different diazide monomers and the proton exchange membrane properties of the copolymers were investigated.


2020 ◽  
Vol 123 ◽  
pp. 109443 ◽  
Author(s):  
Rimpa Chatterjee ◽  
Asheesh Singh ◽  
Anaparthi Ganesh Kumar ◽  
Brigitte Voit ◽  
Susanta Banerjee

e-Polymers ◽  
2017 ◽  
Vol 17 (2) ◽  
pp. 107-118 ◽  
Author(s):  
Asheesh Singh ◽  
Anaparthi Ganesh Kumar ◽  
Soumendu Bisoi ◽  
Sayantani Saha ◽  
Susanta Banerjee

AbstractA series of novel sulfonated polytriazole copolymers (PTFOSH-XX) was successfully prepared by the click reaction of 4,4′-(perfluoropropane-2,2-diyl)bis((prop-2-ynyloxy)benzene (TF), 4,4′-diazido-2,2′-stilbene disulfonic acid disodium salt (SAZ) and 4,4′-diazidodiphenyl ether (OAZ). The copolymers were characterized by Fourier transform infrared (FTIR) and proton nuclear magnetic resonance (NMR) spectroscopy. The copolymers showed high mechanical, thermal and oxidative stability and low swelling. The phase separated morphology of the membranes was confirmed from transmission electron microscopy (TEM). The membranes showed proton conductivity as high as 110 and 122 mS cm−1 at 80 and 90°C, respectively depending on the polymer repeat unit structure.


2013 ◽  
Vol 52 (8) ◽  
pp. 2772-2783 ◽  
Author(s):  
Aruna K. Mohanty ◽  
Ershad A. Mistri ◽  
Susanta Banerjee ◽  
Hartmut Komber ◽  
Brigitte Voit

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