Empirical correlations for second virial coefficients of nonpolar and polar fluids covering a wide temperature range

2021 ◽  
Vol 539 ◽  
pp. 113032
Author(s):  
Liu Xu ◽  
Yuan-Yuan Duan ◽  
Hang-Tao Liu ◽  
Zhen Yang
AIChE Journal ◽  
1971 ◽  
Vol 17 (2) ◽  
pp. 259-265 ◽  
Author(s):  
Roland L. Halm ◽  
Leonard I. Stiel

1976 ◽  
Vol 31 (12) ◽  
pp. 1722-1724 ◽  
Author(s):  
C. Guidotti ◽  
G. P. Arrighini ◽  
M. Capitelli ◽  
U. T. Lamanna

Abstract Second virial coefficients of ground state nitrogen atoms have been calculated in the temperature range 6000 - 20000 K. The results have been obtained using experimental potentials for the states 1∑g+, 3∑u+5∑g+ and of the nitrogen molecule and an ab initio Heitler-London potential for the 2∑u+ repulsive potential. Differences up to a factor of 5 are found between the present second virial coefficients and the corresponding values of Kessel'man et al.


1997 ◽  
Vol 52 (10) ◽  
pp. 748-756
Author(s):  
Ilioara Coroiu ◽  
D. E. Demco

Abstract Second virial coefficients and a large number of Chapman-Cowling collision integrals were calculated for gases obeying an improved intermolecular potential proposed by Aziz et al. [J. Chem. Phys. 94, 1034 (1991)]. The results are tabulated for a large reduced temperature range, kT/ε from 0.1 to 100. The treatment was entirely classical, and no corrections for quantum effects were made. The higher approximations to the transport coefficients were also calculated and tabulated for the same temperature range. These results should be applicable to characterize the bulk properties of various spherical molecules, especially to predict gaseous transport properties. Evaluation of the potential parameters for uranium hexafluoride, together with fitting to second virial coefficient, viscosity, thermal conductivity and self-diffusion data are also presented. This potential appears to have the best overall predictive ability for gaseous hexafluoride data.


1959 ◽  
Vol 12 (3) ◽  
pp. 309 ◽  
Author(s):  
HG David ◽  
SD Hamann ◽  
RB Thomas

This paper reports some measurements of the second virial coefficient B of cyclopropane in the temperature range 300 to 400°K . It also gives some values of B for cyclohexane and benzene, derived from critical analyses of the published vapour densities and P-V-T properties of these gases between 300 and 650°K . In each case the results have been fitted to the relation B = α + β/T + γ/T2 + δ/T3 The following conclusions can be drawn : (i) The values of B for benzene and cyclohexane are consistent with the effects of pressure on the enthalpies and heat capacities of the gases. (ii) cycloHexane and benzene show large and almost equal deviations from the law of corresponding states for monatomic gases, but cyclopropane shows a much smaller deviation. (iii) It is impossible to fit the second virial coefficients of benzene and cyclohexane to the theoretical curve for a Lennard-Jones (12,6) gas. But they can be fitted to the curve for a (28,7) gas, and the associated force constants are physically reasonable. It appears that the interaction potential for cyclopropane molecules is intermediate between the (12,6) and (28,7) potentials.


1982 ◽  
Vol 35 (8) ◽  
pp. 1525 ◽  
Author(s):  
ML Martin ◽  
RD Trengove ◽  
KR Harris ◽  
PJ Dunlop

Excess and interaction second virial coefficients have been measured in the temperature range 290-320 K for 20 binary gaseous systems. Several of these systems have previously been studied by Brewer. The present values are in excellent agreement with his results. The excess virial coefficients have been used to calculate excess molar enthalpies of mixing at 300 K.


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