Free-radical fragmentation reactions of biomolecules involving C-C, C-O and C-N bond cleavage

2018 ◽  
Vol 120 ◽  
pp. S55
Author(s):  
O.I. Shadyro
2018 ◽  
Vol 20 (15) ◽  
pp. 3432-3435 ◽  
Author(s):  
Yunfei Tian ◽  
Anbo Ling ◽  
Ren Fang ◽  
Ren Xiang Tan ◽  
Zhong-Quan Liu

A Cu(ii)-mediated radical anti-Markovnikov hydroalkylation of unactivated alkenes with simple alkanes via selective C(sp3)–H bond cleavage was achieved. This reaction features high site-selectivity, diverse functional group tolerance, and scalability.


2016 ◽  
Vol 1077 ◽  
pp. 2-10 ◽  
Author(s):  
Ana Amić ◽  
Zoran Marković ◽  
Jasmina M. Dimitrić Marković ◽  
Bono Lučić ◽  
Višnja Stepanić ◽  
...  

1990 ◽  
Vol 31 (42) ◽  
pp. 5985-5988 ◽  
Author(s):  
Gordon L Lange ◽  
Christine Gottardo

2019 ◽  
Vol 2019 (27) ◽  
pp. 4422-4425 ◽  
Author(s):  
Yiming Yang ◽  
Guofeng Zhong ◽  
Junfen Fan ◽  
Yunyun Liu

1996 ◽  
Vol 74 (10) ◽  
pp. 1880-1888 ◽  
Author(s):  
Stephen Hanessian ◽  
Sacha Ninkovic

The lactone portion of the podophylotoxin framework was assembled from a free-radical carbocyclization reaction, and the target structure was constructed based on intramolecular Friedel–Crafts reaction. In addition to isodeoxypodophyllotoxin, there were formed unusual tri- and tetracyclic compounds. Key words: free-radical carbocyclization, C—Sn bond cleavage, podophyllotoxin analog.


Sign in / Sign up

Export Citation Format

Share Document