scholarly journals Co catalysts supported on SiO2 and γ-Al2O3 applied to ethanol steam reforming: Effect of the solvent used in the catalyst preparation method

Fuel ◽  
2011 ◽  
Vol 90 (4) ◽  
pp. 1424-1430 ◽  
Author(s):  
A.F. Lucredio ◽  
J.D.A. Bellido ◽  
A. Zawadzki ◽  
E.M. Assaf
2014 ◽  
Vol 39 (24) ◽  
pp. 12586-12596 ◽  
Author(s):  
Jorge Vicente ◽  
Carolina Montero ◽  
Javier Ereña ◽  
Miren J. Azkoiti ◽  
Javier Bilbao ◽  
...  

2013 ◽  
Vol 56 (18-20) ◽  
pp. 1660-1671 ◽  
Author(s):  
Raúl Espinal ◽  
Elena Taboada ◽  
Elies Molins ◽  
Ricardo J. Chimentao ◽  
Francesc Medina ◽  
...  

RSC Advances ◽  
2014 ◽  
Vol 4 (83) ◽  
pp. 43839-43849 ◽  
Author(s):  
F. C. F. Marcos ◽  
A. F. Lucrédio ◽  
E. M. Assaf

2008 ◽  
Vol 80 (11) ◽  
pp. 2397-2403 ◽  
Author(s):  
Salvador Martí ◽  
Narcís Homs ◽  
Evandro Brum Pereira ◽  
Pilar Ramírez de la Piscina

New unsupported Co catalysts were studied in the ethanol steam-reforming reaction by in situ diffuse reflectance infrared spectroscopy and on-line mass spectrometry (MS) techniques. The initial ethoxy surface species evolved to surface-acyl species and to acetaldehyde intermediate at temperatures ca. 473 K. The subsequent formation of surface-acetate species occurs at ca. 573 K. Further, the acetate species mainly evolve above 573 K to H2 and CO2 products. The route to ketone formation was inhibited on these materials. The presence of surface-hydroxyl groups, which are probably related to the formation of a CoO phase under the reforming conditions, was determined. Alkaline addition shows a beneficial effect on the ethanol steam-reforming over bulk Co catalysts.


2021 ◽  
Vol 217 ◽  
pp. 106814
Author(s):  
N. Ferreira ◽  
L. Coronel ◽  
M.S. Moreno ◽  
L.M. Cornaglia ◽  
J.F. Múnera

2014 ◽  
Vol 144 (7) ◽  
pp. 1134-1143 ◽  
Author(s):  
Ana G. Gayubo ◽  
Jorge Vicente ◽  
Javier Ereña ◽  
Carolina Montero ◽  
Martin Olazar ◽  
...  

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