Pentacoordinate cobalt(II) complexes with neutral tripodal N-donor ligands: Zero-field splitting for a distorted trigonal bipyramidal geometry

2018 ◽  
Vol 471 ◽  
pp. 630-639 ◽  
Author(s):  
Salah S. Massoud ◽  
Roland C. Fischer ◽  
Franz A. Mautner ◽  
Megan M. Parfait ◽  
Radovan Herchel ◽  
...  
Keyword(s):  
Donor Ligands ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
Trigonal Bipyramidal Geometry ◽  
Trigonal Bipyramidal ◽  
Distorted Trigonal Bipyramidal

scholarly journals Investigation of the magnetic anisotropy in a series of trigonal bipyramidal Mn(ii) complexes

2019 ◽  
Vol 48 (41) ◽  
pp. 15480-15486
Author(s):  
Moya A. Hay ◽  
Arup Sarkar ◽  
Katie E. R. Marriott ◽  
Claire Wilson ◽  
Gopalan Rajaraman ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
Trigonal Symmetry ◽  
Trigonal Bipyramidal

The trigonal symmetry around the MnII ion is fine-tuned to control the rhombic zero-field splitting.

Correlating the axial Zero Field Splitting with the slow magnetic relaxation in GdIII SIMs

2021 ◽  
Author(s):  
Júlia Mayans ◽  
Albert Escuer
Keyword(s):  
Magnetic Relaxation ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
Slow Magnetic Relaxation

A possible relation between the value of the axial Zero Field Splitting and the occurrence of field-induced slow magnetic relaxation has been established for a new gadolinium(iii) compound.

The role of zero-field splitting and π-stacking interaction of different nitrogen-donor ligands on the optical properties of luminescent rhenium tricarbonyl complexes

2021 ◽  
Author(s):  
Plinio Cantero-López ◽  
Yoan Hidalgo-Rosa ◽  
Zoraida Sandoval-Olivares ◽  
Julián Santoyo-Flores ◽  
Pablo Mella ◽  
...  
Keyword(s):  
Excited States ◽  
Coordination Compounds ◽  
Donor Ligands ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Nitrogen Donor Ligands ◽  
Nitrogen Donor ◽  
Π Stacking Interaction ◽  
Rhenium Tricarbonyl

Rhenium tricarbonyl complexes are one of the most important classes of coordination compounds in inorganic chemistry. Exploring their luminescent excited states, lowest singlet (S1), and the lowest triplet (T1), is...

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