Computational study of the structure and magnetic properties of the weakly-coupled tetranuclear square-planar complex of Cu(II) with a tetraporphyrin sheet

2019 ◽  
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Alina T. Baryshnikova ◽  
Boris F. Minaev ◽  
Gleb V. Baryshnikov ◽  
Hans Ågren
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Zhong-Ning Chen ◽  
Hua-Xin Zhang ◽  
Kai-Bei Yu ◽  
Cheng-Yong Su ◽  
Bei-Sheng Kang

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Kjartan Marøy ◽  
Steinar Husebye ◽  
Svein Solheimsnes ◽  
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Gunner Borch ◽  
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1971 ◽  
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Jacques Emile Guerchais

The study of the far infrared spectral region permits one to distinguish between the pseudo-tetrahedral complexes NiI2L2 (L = R1R2C3S3 where R1 = CH3 and R2 = H, R1 = R2 = CH3, R1 = C4H3S and R2 = H) and the square planar complex NiI2L′2 (L′ = R1R2C3S3 where R1 = C6H5 and R2 = H). The electronic spectra recorded in the solid state confirm the distinction. The displacement of the band νC=S of the molecule 1,2-dithio-1-3-thione which enters the sphere of coordination is more marked in the complexes of cobalt(II) than in the corresponding nickel(II) complexes.


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