Inorganic–organic hybrid with one-dimensional face-sharing iodoplumbate chain showing novel dielectric anomaly and semiconductor emission

A novel bimetallic 4f-3d metal-isonicotinic acid inorganic-organic hybrid complex [{Eu(NC5H4COOH)3(H2O)2}(1.5ZnCl4)?(2H2O)]n (1) was synthesized via a hydrothermal reaction and structurally characterized by single- crystal X-ray diffraction. Complex 1 crystallizes in the space group C2/c of the monoclinic system with eight formula units in a cell: a = 23.878(8) ?, b = 20.573(6) ?, c = 15.358(5) ?, ? = 127.276(5)?, V = 6003(3) ?3, C18H23Cl6EuN3O10Zn1.5, Mr = 904.11 g/mol, ? = 2.001 g/cm3, S = 1.077, ?(MoK?) = 3.846 mm-1, F(000) = 3536, R = 0.0270 and wR = 0.0672. Complex 1 has a characteristic, one-dimensional polycationic chain-like structure. A photoluminescent investigation revealed that the title complex displays intense emissions in the orange and red regions. The luminescence spectra show that the red emission is stronger than the orange emission. Optical absorption spectra of 1 revealed the presence of an optical gap of 3.56 eV.

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A one-dimensional inorganic–organic hybrid compound:catena-poly[ethylenediammonium [indate(III)-di-μ-hydrogenphosphato(V)-μ-hydroxido] monohydrate]

Acta Crystallographica Section E Structure Reports Online ◽

10.1107/s160053681003240x ◽

2010 ◽

Vol 66 (9) ◽

pp. m1065-m1066 ◽

Cited By ~ 1

Author(s):

Abderrazzak Assani ◽

Mohamed Saadi ◽

Lahcen El Ammari

Keyword(s):

One Dimensional ◽

Organic Hybrid

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Investigation of thermochromic photoluminescent, dielectric and crystal structural properties for an inorganic–organic hybrid solid of [1-hexyl-3-methylimidazolium][PbBr3]

New Journal of Chemistry ◽

10.1039/c6nj01508e ◽

2016 ◽

Vol 40 (10) ◽

pp. 8664-8672 ◽

Cited By ~ 10

Author(s):

Kun-Ming Wan ◽

Yuan-Bo Tong ◽

Li-Li Li-Li ◽

Yang Zou ◽

Hai-Bao Duan ◽

...

Keyword(s):

Structural Properties ◽

Dielectric Anomaly ◽

Organic Hybrid ◽

Crystal Structural

An imidazolium-based bromoplumbate hybrid solid shows fascinating luminescence thermochromism, appealing dielectric anomaly and relaxation.

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3d - 4f Heterometallic Complexes for the Construction of POM-based Inorganic - Organic Hybrid Compounds: from Nanoclusters to One-Dimensional Ladder-Like Chains

Australian Journal of Chemistry ◽

10.1071/ch10047 ◽

2010 ◽

Vol 63 (9) ◽

pp. 1389 ◽

Cited By ~ 24

Author(s):

Dongying Du ◽

Junsheng Qin ◽

Shunli Li ◽

Yaqian Lan ◽

Xinlong Wang ◽

...

Keyword(s):

Transition Metal ◽

Transition Metal Complexes ◽

Lanthanide Complexes ◽

Copper Complexes ◽

Heterometallic Complexes ◽

Magnetic Studies ◽

One Dimensional ◽

Organic Hybrid ◽

Hybrid Compounds ◽

Polyanion Chain

Three polyoxometalate-based inorganic–organic hybrid compounds, namely nanoclusters [Cu(en)2H2O]3[(α-SiW11O39)Nd(H2O)(η2,μ-1,1)-CH3COO]·3.5H2O (1) and [Cu(en)2H2O]3[(α-SiW11O39)Sm(H2O)(η2,μ-1,1)-CH3COO]·3H2O (2), and 1D H2[Cu(en)2H2O]8[Cu(en)2]3[{(α-SiW11O39)Ce(H2O)(η2,μ-1,1)-CH3COO}4]·22H2O (3) (en = 1,2-ethylenediamine) have been isolated. 1 and 2 are isomorphic and consist of [(α-SiW11O39)Ln(H2O)(η2,μ-1,1)-CH3COO]6– polyanions modified by [Cu(en)2H2O]2+ fragments. In 3, [Cu(en)2H2O]2+ are grafted on [(α-SiW11O39)Ce(H2O)(η2,μ-1,1)-CH3COO]6– polyanions and further connected by [Cu(en)2]2+ groups, representing the first example in polyoxometalate chemistry of a 1D ladder-like polyanion chain consisting of monovacant Keggin-type polyanions, lanthanide complexes and transition metal complexes. In these compounds, copper complexes coordinate to not only terminal O atoms but also bridging O atoms of the polyanions. Magnetic studies of 1 and 3 reveal weak antiferromagnetic interactions exist in them.

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