Synthesis, structure and proton conductivity of a metal–organic framework with rich hydrogen-bonds between the layers

2017 ◽  
Vol 79 ◽  
pp. 37-40 ◽  
Author(s):  
Min-Yu Li ◽  
Fei Wang ◽  
Jian Zhang
Keyword(s):  
Hydrogen Bonds ◽  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

scholarly journals A confinement of N-heterocyclic molecules in a metal–organic framework for enhancing significant proton conductivity

RSC Advances ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 355-364
Author(s):  
My V. Nguyen ◽  
Thang B. Phan ◽  
Man V. Tran ◽  
Tuyet A. T. Nguyen ◽  
Hung N. Nguyen
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Heterocyclic Molecules ◽  
Metal Organic ◽  
Significant Proton ◽  
Organic Framework

A series of N-heterocyclic⊂VNU-23 materials have been prepared via the impregnation procedure of N-heterocyclic molecules into VNU-23.

scholarly journals Functionality in metal–organic framework minerals: proton conductivity, stability and potential for polymorphism

2019 ◽  
Vol 10 (18) ◽  
pp. 4923-4929 ◽  
Author(s):  
Igor Huskić ◽  
Novendra Novendra ◽  
Dae-Woon Lim ◽  
Filip Topić ◽  
Hatem M. Titi ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
High Proton ◽  
Metal Organic ◽  
Structure Retention ◽  
Organic Framework

Metal–organic framework minerals stepanovite and zhemchuzhnikovite can exhibit high proton conduction and structure retention on dehydration.

Strategic hierarchical improvement of superprotonic conductivity in a stable metal–organic framework system

2019 ◽  
Vol 7 (43) ◽  
pp. 25165-25171 ◽  
Author(s):  
Xiao-Min Li ◽  
Jiang Liu ◽  
Chen Zhao ◽  
Jia-Lin Zhou ◽  
Ling Zhao ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Efficient Strategy ◽  
System P ◽  
Metal Organic ◽  
Framework System ◽  
Organic Framework

An efficient strategy to hierarchically improve the proton conductivity of MOFs by increasing the number of proton sources and hopping sites has been proposed.

Ground to conduct: mechanochemical synthesis of a metal–organic framework with high proton conductivity

2015 ◽  
Vol 51 (36) ◽  
pp. 7637-7640 ◽  
Author(s):  
Dariusz Matoga ◽  
Marcin Oszajca ◽  
Marcin Molenda
Keyword(s):  
Proton Conductivity ◽  
Mechanochemical Synthesis ◽  
Metal Organic Framework ◽  
Environmentally Friendly ◽  
High Proton Conductivity ◽  
Proton Conducting ◽  
High Proton ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

A high proton-conducting metal–organic framework (PCMOF) is prepared for the first time by economical and environmentally-friendly mechanochemistry.

A novel three-dimensional CdIImetal–organic framework based on [Cd6(malonate)6] metallomacrocycles with zeolite SOD (sodalite) topology: poly[ammine-μ3-malonato-cadmium(II)]

2012 ◽  
Vol 68 (3) ◽  
pp. m57-m60
Author(s):  
Shuai Yuan ◽  
Mei-Jiao Liu ◽  
Han-Yi Xie ◽  
Meng-Zhen Xu ◽  
Di Sun
Keyword(s):  
Hydrogen Bonds ◽  
Network Structure ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Liquid Diffusion ◽  
Dimensional Network ◽  
Metal Organic ◽  
Point Symbol ◽  
Organic Framework

A novel CdIImetal–organic framework, [Cd(C3H2O4)(NH3)]n, was synthesized by liquid diffusion conducted in the presence of ammonia. The CdIIatom has seven-coordinate O6N pentagonal–bipyramidal geometry. Six CdIIcenters are joined by six malonate ligands to form anS6-symmetric [Cd6(malonate)6] metallomacrocycle, which is further extended through a side-on chelating malonate ligand to form a three-dimensional network. Topologically, each CdIIcenter is connected to four others to yield an infinite three-periodic four-coordinated SOD (sodalite) network with point symbol {42·64}. The overall network structure in the crystal is maintained and stabilized by the presence of N—H...O hydrogen bonds.

High Proton Conductivity and Spectroscopic Investigations of Metal–Organic Framework Materials Impregnated by Strong Acids

2014 ◽  
Vol 6 (7) ◽  
pp. 5161-5167 ◽  
Author(s):  
Danil N. Dybtsev ◽  
Valentina G. Ponomareva ◽  
Sokhrab B. Aliev ◽  
Alexei P. Chupakhin ◽  
Marsel R. Gallyamov ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
High Proton Conductivity ◽  
Framework Materials ◽  
Spectroscopic Investigations ◽  
High Proton ◽  
Metal Organic ◽  
Strong Acids ◽  
Organic Framework

Roles of hydrogen bonds and π–π stacking in the optical detection of nitro-explosives with a luminescent metal–organic framework as the sensor

RSC Advances ◽  
2015 ◽  
Vol 5 (4) ◽  
pp. 3045-3053 ◽  
Author(s):  
Lei Liu ◽  
Juanyuan Hao ◽  
Yantao Shi ◽  
Jieshan Qiu ◽  
Ce Hao
Keyword(s):  
Hydrogen Bonds ◽  
Metal Organic Framework ◽  
Optical Detection ◽  
Π Stacking ◽  
Nitro Explosives ◽  
Metal Organic ◽  
Organic Framework

The nitro explosive detecting mechanism of a luminescent MOF sensor is revealed from the viewpoint of analyte–sensor interactions.

Increased proton conductivity of metal–organic framework micro-film prepared by a facile salt-free approach

2014 ◽  
Vol 2 (23) ◽  
pp. 8849 ◽  
Author(s):  
Yue Qi ◽  
Shuping Lin ◽  
Chunjiao Chen ◽  
Yuan Liu ◽  
Zhengping Qiao ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework
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