Hydrogenation of tetralin on silica–alumina-supported Pt catalysts I. Physicochemical characterization of the catalytic materials

2007 ◽  
Vol 251 (2) ◽  
pp. 485-496 ◽  
Author(s):  
M WILLIAMS ◽  
B FONFE ◽  
C SIEVERS ◽  
A ABRAHAM ◽  
J VANBOKHOVEN ◽  
...  
2007 ◽  
Vol 251 (2) ◽  
pp. 497-506 ◽  
Author(s):  
M WILLIAMS ◽  
B FONFE ◽  
C WOLTZ ◽  
A JENTYS ◽  
J VANVEEN ◽  
...  

2003 ◽  
Vol 9 (S02) ◽  
pp. 752-753
Author(s):  
J. O. Huertas Flores ◽  
J. R. J. Zumarán Farfán ◽  
M. I. Pais da Silva ◽  
P. M. Jardim ◽  
S. Paciornik

1987 ◽  
Vol 111 ◽  
Author(s):  
Robert L. Augustine ◽  
David R. Baum

AbstractWhile the STO catalyst characterization procedure has been applied to a variety of supported Pt catalysts, application of this technique to the characterization of supported Pd catalysts showed that there were several significant differences between the Pt and the Pd catalysts. Under STO reaction conditions each surface site on a Pt catalyst reacts only once so there is a 1:1 relationship between the product composition and the densities of the various types of active sites present. With Pd catalysts under these same conditions, alkene isomerization takes place so readily that the amount of isomerized product formed depends on the contact time of the reactant pulse with the catalyst so there is no direct relationship between the amount of isomerization and the number of isomerization sites present. On Pt there are some direct saturation sites present on which H2 is rather weakly held. Such sites are not present on Pd catalysts. The reactive surface of supported Pt catalysts remains constant on long exposure to air. With Pd catalysts exposure to air results in a decrease in saturation site densities which can be reversed by re-reduction of the surface with H2 under ambient conditions but not completely under what can be termed “reaction conditions” where the extent of surface re-reduction decreases with catalyst age.


2011 ◽  
Vol 257 (6) ◽  
pp. 2394-2400 ◽  
Author(s):  
Wiktoria Walerczyk ◽  
Mirosław Zawadzki ◽  
Janina Okal

Mining Revue ◽  
2021 ◽  
Vol 27 (4) ◽  
pp. 72-77
Author(s):  
Nurudeen Salahudeen ◽  
Ahmad A. Mukhtar

Abstract In their raw forms, clay minerals are found with a number of inherent impurities which make them unsuitable for most industrial applications. In order to overcome this problem and add value to clay minerals, beneficiation process is an indispensable solution. This study investigates effect of wet beneficiation process on the characteristics of a local clay mined from Getso village of Kano State, Nigeria. Mineralogical characterization of the clay was carried out using X-ray diffraction (XRD) analyzer. Chemical characterization of the clay was carried out using X-ray fluorescence analyzer. Physicochemical characterization of the clay was carried out using pH meter and density analysis conducted using density bottle. XRD analysis of Getso clay showed that the raw clay had 8 wt% kaolinite and 51% quartz. Wet beneficiation resulted into 53% improvement of the kaolinite content and 47% reduction of quartz impurity. The XRF analysis has shown that silica-alumina ratio of the raw Getso clay was 1.55 and this reduced to 1.49 after beneficiation. The physicochemical characterization of the clay has shown that Getso clay is neutral, the raw clay and beneficiated clay had average pH values of 7.5 and 7.3, respectively. Specific gravity values of the raw and beneficiated clay were 2.24 and 2.04, respectively. The beneficiation process had been effective as substantial increase in kaolinte content was observed and a reasonable decrese in the impurity contents was observed from the raw to the beneficiated clay. The Garnet content was completely reduced to zero while quartz, clinochlore and orthoclase were reduced by 24%, 9% and 13% respectively. The clay obtained after the beneficiation be serve as good raw material for production of whitewares, high grade ceramics in synthesis of zeolitic materials.


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