Modeling the Viscoelastic Behavior of Quartz and Clay Minerals in Shale by Nanoindentation Creep Tests

The viscoelastic behavior of minerals in shales is important in predicting the macroscale creep behavior of heterogeneous bulk shale. In this study, in situ indentation measurements of two major constitutive minerals (i.e., quartz and clay) in Longmaxi Formation shale from the Sichuan Basin, South China, were conducted using a nanoindentation technique and high-resolution optical microscope. Firstly, quartz and clay minerals were identified under an optical microscope based on their morphology, surface features, reflection characteristics, particle shapes, and indentation responses. Three viscoelastic models (i.e., three-element Voigt, Burger’s, and two-dashpot Kelvin models) were then used to fit the creep data for both minerals. Finally, the effects of peak load on the viscoelastic behavior of quartz and clay minerals were investigated. Our results show that the sizes of the residual imprints on clay minerals were larger than that of quartz for a specific peak load. Moreover, the initial creep rates and depths in clay minerals were higher than those in quartz. However, the creep rates of quartz and clay minerals displayed similar trends, which were independent of peak load. In addition, all three viscoelastic models produced good fits to the experimental data. However, due to the poor fit in the initial holding stage of the three-element Voigt model and instability of the two-dashpot Kelvin model, Burger’s model is best in obtaining the regression parameters. The regression results indicate that the viscoelastic parameters obtained by these models are associated with peak load, and that a relatively small peak load is more reliable for the determination of viscoelastic parameters. Furthermore, the regression values for the viscoelastic parameters of clay minerals were lower than those of quartz and the bulk shale, suggesting the former facilitates the viscoelastic deformation of shale. Our study provides a better understanding of the nanoscale viscoelastic properties of shale, which can be used to predict the time-dependent deformation of shale.

Soil additives immobilising heavy metals in contaminated soils

Addition of iron oxides, lime, clay minerals and other substances can be used to decrease the plant availability of toxic heavy metals such as Pb, Zn, and Cd. Extractability and consequently plant concentrations may be reduced in some cases by more than 50%. The assessment of remediation processes is supported by biomonitoring methods in the field with Plantago lanceolata and in the greenhouse by barley test experiments, in combination with extraction by ammonium nitrate.

Diagenetic Fluid and Its Impact on Sandstone Reservoirs in the Southern Boxing Sag, Dongying Depression, Bohai Bay Basin, China

Diagenesis typically exerts a crucial impact on the formation of high-quality sandstone reservoirs in the Eocene Shahejie Formation, Dongying Depression. To better understand the formation process of petrophysical properties, this research conducts petrographic and geochemical analyses to investigate the nature of diagenetic fluids. Petrographic observations suggest that the dominant cements are carbonate, authigenic quartz, and clay minerals, accompanied with the dissolution of feldspar and calcite. The homogenization temperature of aqueous inclusions in quartz overgrowth usually exceeds 90°C corresponding to the maturity of organic matter. Quartz overgrowths contain higher amounts of CaO and Al2O3 than detrital quartz. This indicates that the siliceous fluid mainly originates from the dissolution of feldspar. Moreover, the conversion of clay minerals also provides trace amounts of silica into pore water during the burial process. Carbonate cements consist of early-stage calcite as well as late-stage Fe-calcite and ankerite. Calcite with relatively higher MnO proportions shows yellow luminescence and dissolution signs. Fe-calcite and ankerite cements have a higher homogenization temperature than that of quartz overgrowth and mainly concentrate in FeO and MgO as well as contain a small amount of Na+, K+, and Sr2+. The rare earth element (REE) pattern of bulk mudstone and carbonate cements as well as C–O isotopic evidences indicate that the diagenetic fluids of carbonate cementation are primarily controlled by the adjacent mudstone, whereas mineral dissolution and altered clay minerals in sandstone provide additional cations for the local reprecipitation of late-stage carbonate. Therefore, diagenetic fluids within sandstone reservoirs are typically subject to alkaline–acid–alkaline conditions and are influenced by internal sources in a closed system. Compaction significantly reduces the pore space of sandstone reservoirs in the Boxing Sag. Carbonate cementation further increases the complexity of pore structure and obeys the principle of mass balance.

The Fourier transform infrared spectroscopy (FTIR) analysis for the clay mineralogy studies in a clastic reservoir

The complete characteristics knowledge of clay minerals is necessary in the evaluation studies of hydrocarbon reservoirs. Ten samples taken from two wells in a heterogeneous clastic gas reservoir formation in NE Iran were selected to conduct the transmission Fourier transform infrared spectroscopy (FTIR) tests for the clay mineralogy studies. The FTIR analysis showed that there were clear signs of clay minerals in all samples. The wavenumber region of the clay minerals in FTIR tests was detected to be 3621, 3432, 1034, and 515 cm−1 for illite, 3567, 3432, 1613, 1088, 990, 687, 651, and 515 cm−1 for magnesium-rich chlorite, 3700, 3621, 3432, 1034, 687, and 463 cm−1 for kaolinite, and 3567, 1088, 990, and 463 cm−1 for glauconite. After screening of samples by the FTIR method, the samples were then analyzed by powder X-ray diffraction (PXRD), wavelength dispersive X-ray fluorescence (WDXRF), and scanning electron microscopy (SEM). The PXRD and SEM result showed illite was by far the most common clay present. Kaolinite, magnesium-rich chlorite, and traces of smectite and the mixed-layer clays of both the illite–smectite and chlorite-smectite types were also recognized. The combination of PXRD and WDXRF results could quantify the clay abundances in the each well too. It was concluded that the FTIR analysis successfully could show the absorption bonds of all constituent clays. However, the infrared absorption spectra of mixed-layer clays overlapped those of the respective constituents of each mixed-layer minerals. This can be considered as the evidence of the usefulness of FTIR technique in the screening of the samples for the clay mineralogy studies.

Editorial for Special Issue “Clay Minerals and Waste Fly Ash Ceramics”

This Special Issue published a collection of eight scientific contributions [...]

Trends and Composition—A Sedimentological-Chemical-Mineralogical Approach to Constrain the Origin of Quaternary Deposits and Landforms—From a Review to a Manual

In this study, six basic Quaternary landform series (LFS) and their sedimentary deposits (LFS1 aeolian, LFS 2.1 to 2.2 mass wasting, LFS 3 cryogenic-glacial, LFS 4.1 to 4.6 fluvial, LFS 5.1 to 5.2 coastal-marine, LFS 6.1 to 6.3 lacustrine) are subdivided into subtypes and examined with regard to their sedimentological parameters and their mineralogical and chemical compositions. Emphasis is placed on the textural (related to transport and deposition), compositional (sediment load/weight, Eh and pH) and geodynamic maturity of the sedimentary deposits which are influenced by the parent lithology and bedrock tectonic and by the climate during the last 2 Ma. To constrain the development of the LFS and their sediments, composite trend-line diagrams are designed combining sedimentological (x-axis) and chemical/mineralogical dataset (y-axis): (1) sorting vs. heavy mineral content; (2) sphericity of grains vs. silica/carbonate contents; and (3) median vs. Ti/Fe ratios. In addition, the x-y plots showing the log SiO2/Al2O3 vs. log Na2O/K2O are amended by a dataset of the three most common clay minerals, i.e., kaolinite-, mica-, and smectite-group clay minerals. Such joint sedimentological-chemical-mineralogical investigations focused on the depositional environment of unconsolidated clastic sediments of Quaternary age can be used to describe the economic geology and environmental geology of mineral deposits in the pre-Quaternary sedimentary series according to the phrase: “The Present is the key to the Past”. Both trend diagrams and compositional x-y plots can contribute to constraining the development of the full transect of landform series from the fluvial incision and slope retreat to reef islands fringing the coastal zone towards the open sea as far as they are built up of clastic sedimentary deposits enriched in siliceous and/or carbonate minerals. Climate zonation and crustal maturity are the exogenous and endogenous “drivers”, as can be deduced from the compositional (mineralogy and chemistry) and physical (transport and deposition) variations observed in the Quaternary sediments. The current study bridges the gap between a review only based on literature and a hybrid manual generated by practical field studies devoted to applied geosciences in economic and environmental geology (“E & E issue”).