Thermodynamic studies on the interactions of diglycine with magnesium chloride in aqueous medium at different temperatures

2006 ◽  
Vol 38 (12) ◽  
pp. 1592-1605 ◽  
Author(s):  
Bhajan S. Lark ◽  
Poonam Patyar ◽  
Tarlok S. Banipal
1968 ◽  
Vol 21 (3) ◽  
pp. 641 ◽  
Author(s):  
RS Saxena ◽  
KC Gupta ◽  
ML Mittal

Potentiometric and conductometric studies of the nickel-thiomalic acid system, in aqueous medium of 0. lM KNO3, reveal the formation of two complexes; one light violet 1 : 1 predominating at pH 6.5-7.5 and another deep violet 1 : 2 in the pH range 8.5-10.0. The stability constants of the complexes formed have been determined by applying Calvin and Melchior's extension of Bjerrum's method at three different temperatures and were further refined by using alternative methods. The logK values (final) for 1 : 1 and 1 : 2 complexes at 20, 25, and 30� have been found to be 7.86, 7.87, 7.96, and 6.24, 6.31, 6.39 respectively. The values of the overall changes in ΔG, ΔH, and ΔS accompanying the reaction have also been evaluated at 25� and found to be -19.31 kcal/mole, -8.77 kcal/mole, and +35.36 cal/deg respectively.


Ionics ◽  
2015 ◽  
Vol 21 (8) ◽  
pp. 2237-2245 ◽  
Author(s):  
Mu. Naushad ◽  
Z. A. ALOthman ◽  
Md. Rabiul Awual ◽  
Mohammad Mezbaul Alam ◽  
G. E. Eldesoky

2016 ◽  
Vol 22 (1) ◽  
pp. 242-245 ◽  
Author(s):  
. A. Debnath ◽  
. A. Thakur ◽  
. K. L. Bhowmik ◽  
. A. Bera ◽  
. B. Saha

2013 ◽  
pp. 130422000216009
Author(s):  
Malik Abdul Rub ◽  
Abdullah M. Asiri ◽  
Naved Azum ◽  
Anish Khan ◽  
Aftab Aslam Parwaz Khan ◽  
...  

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